含硫油品储罐热自燃事故的早期规律  

Early regularity on the spontaneous combustion accident of oil storage tank containing sulfur

作　　者：赵冬[1] 蒋军成[1] 赵声萍[1] 窦战 毛光斌 

机构地区：[1]南京工业大学城市建设与安全工程学院,江苏南京211816

出　　处：《消防科学与技术》2013年第11期1186-1188,共3页Fire Science and Technology

基　　金：国家自然科学基金资助项目(51176070)

摘　　要：搭建了模拟合硫油品储罐腐蚀产物的硫化试验装置，制备引发舍硫油品储罐自燃火灾的铁锈模拟物的硫化腐蚀产物试验样品，以硫化产物为基础进行氧化实验，研究腐蚀产物的氧化规律。结果表明，硫化产物的氧化反应前期升温明显，温升梯度逐渐增大；氧气体积分数越大，氧化达到的最高温度越高，所用时间越短；将氧气体积分数控制在3．0％～5．0％，可以有效地控制铁锈模拟物硫化产物的氧化放热。The sulfuration experiment equipment was built. Through this equipment, the sulfurized products of simulated rust can be prepared. These testing samples are the material ba- ses of the oxidization experiments. Results showed that the ear- ly stage of oxidization of sulfurized products has significant tem- perature rise, and the temperature gradient increase too; the bigger the oxygen concentration, the higher the temperature peak value, and the shorter the time needed; controlling the ox- ygen concentration in the range from 3.0 % to 5.0%, can effec tively control the exothermic oxidation of the sulfurized prod uets.

关 键 词：氧气体积分数 硫化产物 自燃倾向性 氧化规律 

分 类 号：X913.4[环境科学与工程—安全科学] TE972[石油与天然气工程—石油机械设备]