荷电纳滤膜的DSPM传质模型及其发展  

DSPM-type mass transfer model and its development for charged nanofiltration membranes

作　　者：王钊[1] 徐一涵[1] 贾玉玺[1] 石彤非[2] 

机构地区：[1]山东大学材料液固结构演变与加工教育部重点实验室,山东济南250061 [2]中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,吉林长春130022

出　　处：《功能材料》2013年第22期3230-3234,3238,共6页Journal of Functional Materials

基　　金：国家重点基础研究发展计划(973计划)资助项目(2012CB821505);中国科学院知识创新工程重要方向资助项目(KJCX2-YW-H19);山东省自然科学杰出青年基金资助项目(JQ201016)

摘　　要：纳滤膜是一种重要的分离功能膜。发展一种既能描述纳滤过程基本物理现象又具有应用价值的离子截留模型是纳滤科学领域的一大挑战。从纳滤分离机理和模型建立两方面,对基于扩展的NernstPlanck方程的道南位阻孔模型(DSPM)进行了总结,综述了考虑浓差极化层的CP-DSPM模型、考虑介电效应的DSPM&DE模型以及同时考虑两种影响因素的PPTM模型。采用上述4种模型,基于有限元模拟方法获得了溶液渗透通量与离子截留率的关系曲线,并开展了比较性分析。最后简述了荷电纳滤膜DSPM模型以及纳滤技术的发展方向。Nanofihration was a very useful separation process having many industrial applications. The prediction of separation performances requires the understanding of the various physical phenomena governing the mass transfer through the membrane. It remains as a challenge in the field of nanofiltration to develop a practi- cal model for the retention of ions that describes the fundamental physical phenomena of nanofihration process. This paper summarizes the DSPM-type mass transfer model which was based on the extended Nernst Planck e- quation, which was constructed for the prediction of the separation efficiency with a minimum of characteriza- tion experiments. As the supplement of DSPM, CP-DSPM which involved a concentration polarization layer, DSPM ＆DE which concerned dielectric exclusion, and PPTM which considered the above two factors are re- viewed. In addition, lhe numerically simulaled resuhs of ion rejections under conditions of different water fluxes by means of the above-mentioned four models are compared. I.astly, the development tendency of the nano- filtration science and DSPM model was presented.

关 键 词：纳滤膜 DSPM CP DSPM DSPM&DE PPTM 

分 类 号：TQ028.8[化学工程]