全氟烷基醇的合成  

Synthesis of Perfluoroalkyl Alcohol

作　　者：王世新 张恒英 

机构地区：[1]太仓环保化工有限公司,江苏太仓215433

出　　处：《广州化工》2013年第22期23-24,54,共3页GuangZhou Chemical Industry

摘　　要：全氟烷基醇是重要的含氟中间体,广泛用于织物整理剂、表面活性剂、含氟树脂和医药中间体等领域。本文综述了其主要的合成方法:电解氟化法,调聚法和酯化水解法,重点介绍了以酯化水解法合成全氟烷基乙醇,并指出各种合成方法的优缺点。对其市场状况及研究发展进行分析展望,为实现其工业化研究提供必要的技术支持。Perfluoroalkyl alcohols were important fluorinated intermediates, widely used in textile finishing agent, surfactant, fluoro - resin and pharmaceutical intermediates and other fields. The synthesis of perfluoroalkyl alcohols using the electrolyte fluorination, telomerixation and esterfieation - hydrolyzation were summarized, the emphasis was on the synthesis of perfluoroalkyl ethyl alcohol by esterification - hydrolyzation method, and the advantages and disadvantages of various synthetic methods were pointed out. The analysis forecasted the market situation and research development for the perfluoroalkyl alcohols to provide technological support for the realization of its industrialization.

关 键 词：全氟烷基醇 含氟织物整理剂 酯化水解法 

分 类 号：TQ223.1[化学工程—有机化工]