喹啉氧基乙酰胺型配体镉配合物的合成、晶体结构及荧光性质（英文）  

A Cadmium(Ⅱ) Complex with a Quinolinyloxy Acetamide Ligand:Synthesis, Crystal Structure and Fluorescence Spectra

作　　者：叶行培 吴伟娜[1] 李飞飞[1] 蔡红新[1] 王元[1] 

机构地区：[1]f河南理工大学物理化学学院,焦作454000

出　　处：《无机化学学报》2013年第12期2678-2682,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.21001040);河南省科技厅基础与前沿研究项目(No.132200410404);河南省教育厅自然科学基金(No.12B150011);河南理工大学青年骨干教师项目(No.649210)资助项目

摘　　要：合成并通过单晶衍射表征了一个配合物[CdL(H2O)(NO3)]NO3·CH3COCH3(1)(L=N-甲基N-苯基-2-(8-喹啉氧基)乙酰胺)。在配合物1中,金属镉离子采取扭曲的八面体配位构型。来自配体L的1个氧原子和2个氮原子,2个硝酸根的2个氧原子及配位水分子的1个氧原子与中心镉离子配位。配合物通过分子间的O-H…O氢键作用构筑成沿a轴的一维链状结构。乙腈溶液中配体L和配合物1均在390 nm有荧光发射,但配合物的荧光强度要远低于配体。[CdL（H20）（NO3）]NO3.CH3COCH3 （1） （L=N-methyl-N-phenyl-2-（quinolin-8-yloxy）acetamide）, was synth- esized and characterized by X-ray diffraction. In complex 1, the Cd（II） center is coordinated with two O atoms and one N atom from one ligand L, two 0 atoms from two mono-dentate nitrate anions and one O atom from one water molecule, possessing a distorted octahedral coordination geometry. In the crystal, intramolecular O-H ... O hydrogen bonds between the coordinated water molecules and free nitrate O atoms link the complexes into chains along the a axis. In CH3CN solution, both ligand L and complex 1 exhibit emission band at 390 ran. However, the emission intensity of 1 is much lower than that of the ligand L. CCDC： 958121.

关 键 词：8-羟基喹啉 乙酰胺 镉配合物 晶体结构 荧光 

分 类 号：O614.242[理学—无机化学]