Grafting β-CD Copolymer Metal Complex from Silicon Gel by SI-ATRP  

作　　者：JIANG Yan LIANG Yuan ZHANG Hong-wen ZHANG Rong 

机构地区：[1]School of Materials Science & Engineering, Changzhou University, Changzhou 213164, P.R.China

出　　处：《Chemical Research in Chinese Universities》2013年第6期1029-1031,共3页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（Nos.51203015, 51243003）.

摘　　要：Polymers grafted from solid surface are being extensively studied with a range of objectives.The most popular living/controlled polymerization used in polymers grafted from solid surfaces is the surface-initiated atom transfer radical polymerization（SI-ATRP）[1,2].An attractive feature of atom transfer radical polymerization（ATRP） is to simultaneously grow chains from multifunctional surface.Thus the grafted polymer with well-defined structures could be designed and controlled.ATRP has proven to be a powerful tool to synthesize homopolymers and copolymers,under easily accessible experimental conditions[3-7].Furthermore it is useful for the functionalization of material surfaces by grafting certain polymers.Polymers grafted from solid surface are being extensively studied with a range of objectives.The most popular living/controlled polymerization used in polymers grafted from solid surfaces is the surface-initiated atom transfer radical polymerization（SI-ATRP）[1,2].An attractive feature of atom transfer radical polymerization（ATRP） is to simultaneously grow chains from multifunctional surface.Thus the grafted polymer with well-defined structures could be designed and controlled.ATRP has proven to be a powerful tool to synthesize homopolymers and copolymers,under easily accessible experimental conditions[3-7].Furthermore it is useful for the functionalization of material surfaces by grafting certain polymers.

关 键 词：Silicon gel Surface-initiated atom transfer radical polymerization Copolymer metal complex 

分 类 号：O632.13[理学—高分子化学] O641.4[理学—化学]