含酞菁功能基聚苯胺的合成及性能研究Ⅰ.酞菁铜磺酸掺杂聚苯胺的合成与表征  

SYNTHESIS AND CHARACTERIZATION OF POLYANILINE CONTAINING PHTHALOCYANINE I.SYNTHESIS AND CHARACTERIZATION OF POLYANILINE DOPED BY Cu SULFOPHTHALOCYANINE

作　　者：封伟[1] 韦玮[2] 吴洪才 万梅香[3] 

机构地区：[1]西安交通大学电信学院物理电子光电系,陕西西安710049 [2]西安交通大学化工学院高分子系 [3]中国科学院化学研究所

出　　处：《高分子材料科学与工程》2000年第6期61-64,共4页Polymer Materials Science & Engineering

基　　金：国家自然科学基金资助项目!(19775 0 39);西安交通大学科研基金资助;中国科学院有机固体开放实验室资助项目

摘　　要：以耐晒翠蓝为原料合成了酞菁铜磺酸 (Cu Pc S) ,用其对本征态聚苯胺分别在水相和油相中进行掺杂 ,获得了具有酞菁功能基聚苯胺的分子结构。该聚合物具有优良的溶解性能和成膜能力 ,电导率达到 10 S/ m ,红外谱图证实了所合成产物的结构 ,紫外吸收分析表明 ,用酞菁铜磺酸掺杂聚苯胺后在可见光区、近红外区具有较强的吸收 。Using sodium Cu sulfophthalocyanine as material, Cu sulfophthalocyanine was synthesized. Polyaniline in eigenstate was doped with Cu sulfophthalocyanine in water phase and oil phase respectively. The photoconductive polymer polyaniline containing phthalocyanine was obtained. The polymer has high solubility, fine ability to film, and conductivity reach 10 S/m. The chemical structure of the polymer was identified by IR. The absorption of polyaniline doped with Cu sulfophthalocyanine is very intense in the range of visible light and near infrared. The photoconductivity of the polymer is greatly enhanced.

关 键 词：光电导功能高分子 酞菁铜磺酸 聚苯胺 掺杂 

分 类 号：O632.62[理学—高分子化学]