Mg-6wt%Zn-1wt%Mn合金中的析出相演变(英文)  

Precipitate Evolution in Mg-6 wt%Zn-1 wt%Mn Alloy

作　　者：石国梁[1] 张丁非[2] 赵霞兵[2] 张奎[1] 李兴刚[1] 李永军[1] 马鸣龙[1] 

机构地区：[1]北京有色金属研究总院有色金属材料制备加工国家重点实验室,北京100088 [2]重庆大学,重庆400045

出　　处：《稀有金属材料与工程》2013年第12期2447-2452,共6页Rare Metal Materials and Engineering

基　　金：National Great Theoretic Research Project(2007CB613700);National Sci&Tech Support Project(2011BAE22B03-3);International Cooperation Project(2010DFR50010,2008DFR50040);Chongqing Sci&Tech Project(CSTC,2010AA4048)

摘　　要：通过透射电子显微技术（TEM）研究了Mg-6wt％Zn．1wt％Mn（ZM61）合金在单级和双级时效过程中过渡相β1’和β2’的演变规律以及β1’杆状相在α-Mn颗粒上异质形核的原因。ZM61合金在不同温度的硬化曲线（130、160、180、200、230℃）均表明：与单级时效相比，双级时效的硬化效果更好同时硬化速率更快。由于β1’杆状相的表面能和形核能垒均小于β2’盘状相，因此，峰时效之前主要发生β1’杆状相的快速形核和伸长；β1’杆状相体积分数的增加在带来硬度增加的同时也提升了体系的应变能，β2’盘状相取代β1’杆状相可以释放这一累积的应变能，因而过时效阶段主要发生β2’盘状相对β1’杆状相的逐步取代。ZM61合金在预时效后（90℃／24h），组织中存在高弥散度的GP．区（-10nm），它们可以作为第二级时效过程中β1·杆状相的形核核心，从而大幅提升了杆状相的弥散度。由于β1’杆状相在α-Mn颗粒上异质形核可以形成β1’／α-Mn共格界面，取代之前的非共格的α-Mn版-Mg界面，从而有效降低了体系的界面能，因此时效态组织中普遍存在β1’杆状相在α-Mn颗粒上异质形核的现象。The evolution rules of transitional phases β＇ and β＇ during single and double aging and the heterogeneous nucleation of β＇ rods on a-Mn particles in a Mg-6 wt%Zn-lwt%Mn （ZM61） alloy were studied by TEM technique. Age-hardening curves （130, 160, 180, 200 and 230 ℃） show that double aging can more greatly enhance hardening level and rate than single aging. The rapid nucleation and the elongation of β1＇ rods occupies the stage before peak aging; the volume fraction increase of β＇ rods results in hardness rise and also a huge accumulation of strain energy; in the over-aging stage the growth offl2＇ discs at the cost of β＇ rods can effectively relieve such a strain energy accumulation. G. P. zones of about 10 nm in diameter are densely distributed in matrix after the pre-aging （90 ℃/24 h）, which can act as the heterogeneous nuclei for β＇ rods and thus considerably raise their number density. Moreover, β＇ rods tiequantly heterogeneously nucleate on a-Mn particles, because such heterogeneous nucleation can result in a coherent β＇/a-Mn interface and thus reduce the interfacial energy.

关 键 词：ZM61镁合金 析出相演变 双级时效 α-Mn 异质形核 

分 类 号：TG146.22[一般工业技术—材料科学与工程]