基于同步辐射光电离质谱的燃烧与能源研究新方法  

Novel applications of synchrotron VUV photoionization mass spectrometry in combustion and energy research

作　　者：贾良元[1,2] 周忠岳[1,2] 李玉阳[1,2] 杨玖重[1,2] 齐飞[1,2] 

机构地区：[1]国家同步辐射实验室 [2]中国科学技术大学,合肥230029

出　　处：《中国科学：化学》2013年第12期1686-1699,共14页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金项目(50925623);国家重点基础研究发展计划项目(973项目,2013CB834602)资助;中国科学院支持

摘　　要：化石燃料为当今世界提供了超过80%的能源,其大量消耗所引起的能源危机和环境问题已成为全球关注的热点问题.解决此问题的关键在于深入理解燃烧和能源转化过程中的化学反应机理,进而从本质上探寻提高燃烧效率与减少污染物排放的方法.本文回顾了本课题组近年来发展的多种基于同步辐射光电离质谱技术的新方法和新装置,及其在燃烧与能源研究中的应用,并对未来可以发展的新方法和新方向进行了展望.Combustion of fossil fuels provides more than 80% of the global energy supply nowadays. However, the rapid consumption of fossil fuels has raised great public concerns on energy sustainability and environmental security. Since chemical reactions play the crucial role in combustion and other thermal chemical processes in energy conversion, prior understanding of the chemical reaction mechanisms in these processes is essential for exploring new techniques to improve combustion efficiency and reduce pollutant emissions. This paper reviews our recent efforts in the development of new methods and instruments with synchrotron vacuum ultraviolet （VUV） photoioni- zation mass spectrometry and their applications in combustion and energy research, and presents perspectives of novel methods and applications in the near future.

关 键 词：同步辐射真空紫外光电离质谱 新方法新装置 燃烧化学 能源转化中热化学过程 

分 类 号：O643.21[理学—物理化学]