2种含三嗪环单体的合成与表征  

Synthesis and characterize of two kinds of monomer with triazin

作　　者：武永刚[1,2] 刘楠[1,2] 马波 

机构地区：[1]河北大学生命科学学院,河北保定071002 [2]河北大学生物技术研究中心,河北保定071002

出　　处：《河北大学学报（自然科学版）》2013年第6期614-619,共6页Journal of Hebei University(Natural Science Edition)

基　　金：教育部博士点基金资助项目(20091301120004);河北大学校内基金资助项目(Y2008134)

摘　　要：基于三聚氯氰的逐次取代效应,以其和乙醇胺为原料制备了2种新型含三嗪环ABB′活性单体,即2-(4,6-二氯-1,3,5-三嗪)-氧乙基三氟乙酸铵(活性单体a)和2,4-二氯-6-羟乙氨基-1,3,5-三嗪(活性单体b),探讨了反应条件对产率的影响.利用傅里叶变换红外光谱仪(FTIR)、液相色谱-质谱联用仪(LC-MS)和核磁共振光谱仪(NMR)等仪器对活性单体和聚合物进行了表征.Because of its chemoselective reactivity,the authors synthesized two 1,3,5-triazin deriva- tives of 2-（4,6-dichloro-1,3,5-triazin）-oxygen ammonium trifluoro acetate and 2,4-dichloro-6-hydroxyeth- ylamino-1,3,5-triazine defined as novel ABB′active-monomer a and active-monomer b,which contained triazine from cyanuric chloride and ethanolamine.The effect of reaction conditions on the conversion was investigated.The products were characterized by FTIR,DSC,TG,LC-MS,NMR and so on.

关 键 词：三聚氯氰 乙醇胺 2-(4 6-二氯-1 3 5-三嗪)-氧乙基三氟乙酸铵 2 4-二氯-6-羟乙氨基-1 3 5-三嗪 

分 类 号：Q55[生物学—生物化学]