攀枝花预氧化钛精矿的H2还原行为  

Reduction behavior of Panzhihua pre-oxidized ilmenite by hydrogen

作　　者：危雪梅[1] 鲁雄刚[1] 肖玮[1] 

机构地区：[1]上海大学上海市现代冶金与材料制备重点实验室,上海200072

出　　处：《中国有色金属学报》2013年第11期3248-3253,共6页The Chinese Journal of Nonferrous Metals

基　　金：国家自然科学基金资助项目(51074105);国家杰出青年科学基金资助项目(51225401)

摘　　要：采用热重分析、X射线衍射、扫描电镜和光学显微镜等技术对攀枝花预氧化钛精矿的H2还原行为进行研究，包括H 2还原反应的动力学、还原产物的物相转变及显微结构的变化规律。结果表明：预氧化钛精矿在1100℃还原80 min后还原度达到96.04%；在温度为1000~1150℃范围内，还原过程受界面化学反应控制，表观活化能为95.25 kJ/mol。在还原过程中将会形成M 3 O 5型（M=Ti, Fe, Mg等）固溶体，导致还原难度加大。显微结构表明，还原反应由颗粒边缘向内部进行，而Mg元素在未反应内核的富集阻碍了预氧化钛精矿的进一步还原。Reduction behavior of Panzhihua pre-oxidized ilmenite in hydrogen atmospheres, such as reduction kinetic, phase transformation and microstructures of reduced products was investigated by thermo-gravimetric , X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, and optical microscopy. The results show that the reduction degree reaches 96.04% when the pre-oxidized ilmenite concentrates are reduced at 1 100 ℃ for 80 min and the reduction reaction is controlled by interfacial chemical reaction with the activation energy of 95.25 kJ/mol at 1 000-1 150 ℃. The M3O5 （Mis Fe, Ti, Mg, etc） solid solution forms in the reduction process, in which the reduction difficulty increases. Microstructure analysis shows that the reaction takes place from the exterior of the grain to its interior and the enrichment of Mg in the unreacted area restricts the further reduction of pre-oxidized ilmenite.

关 键 词：预氧化钛精矿 H2 还原 动力学 物相 显微结构 

分 类 号：TF533[冶金工程—钢铁冶金]