石灰乳法制备四氧化三锰  

Preparation of manganese tetroxide with lime milk

作　　者：杨志超[1] 冯雅丽[1] 李浩然[2] 刘欣伟[1] 王维大[1] 周宇照[1] 滕青[1] 

机构地区：[1]北京科技大学土木与环境工程学院,北京100083 [2]中国科学院过程工程研究所生化工程国家重点实验室,北京100190

出　　处：《中国有色金属学报》2013年第11期3254-3259,共6页The Chinese Journal of Nonferrous Metals

基　　金：国家高技术研究发展计划资助项目(2012AA062401);国际海域资源调查与开发专项(DY125-15-T-08)

摘　　要：研究氯化锰与石灰乳制备四氧化三锰,并采用正交实验考察石灰乳浓度为1 mol/L时,Mn2+浓度、反应温度、石灰乳加料速度对氢氧化锰纯度的影响。正交实验结果表明,氯化锰浓度为0.5 mol/L、反应温度为80℃、加料速度为6 mL/min时,氢氧化锰中锰含量可达60%以上,初级产品四氧化三锰中锰含量为70.42%。X射线衍射、化学多元素和红外分析显示,初级产品四氧化三锰中的主要杂质为氧化钙和碱式氯化锰。碱式氯化锰可通过氢氧化钠溶液处理而去除。热力学计算和实验结果表明,水热法可同时除去杂质氧化钙和碱式氯化锰,最终产品锰含量可达71.27%。Manganese tetroxide was prepared with manganese chloride and lime milk. The influences of manganese ion concentration, reaction temperature and feeding speed were investigated through orthogonal experiments when the concentration of lime milk is 1 mol/L. The results show that the manganese in manganese hydroxide is above 60%when the feeding speed is 6 mL/min with manganese ion concentration of 0.5 mol/L and at 80℃. The content of manganese in the product is 70.42%. The results of X-ray diffraction, chemical multi-element and infrared analysis show that calcium oxide and basic manganese chloride are main impurities in the manganese tetroxide primary products. Basic manganese chloride can be removed by the processing of sodium hydroxide solution. The thermodynamic calculations and experimental results indicate that the hydrothermal method can eliminate the impurities of calcium oxide and basic manganese chloride simultaneously, and the content of final products manganese is up to 71.27%.

关 键 词：石灰乳 碱式氯化锰 四氧化三锰 水热法 

分 类 号：TF111.31[冶金工程—冶金物理化学]