湘南宝山铅锌多金属矿区花岗闪长斑岩及其暗色包体成因：锆石U-Pb年代学、岩石地球化学和Sr-Nd-Hf同位素制约  

Origin of granodiorite porphyry and mafic microgranular enclave in the Baoshan Pb-Zn polymetallic deposit,southern Hunan Province: Zircon U-Pb chronological,geochemical and Sr-Nd-Hf isotopic constraints

作　　者：谢银财 陆建军[1] 马东升[1] 章荣清[1] 高剑峰 姚远[4] 

机构地区：[1]内生金属矿床成矿机制研究国家重点实验室南京大学地球科学与工程学院,南京210093 [2]中国地质科学院岩溶地质研究所国土资源部、广西壮族自治区岩溶动力学重点实验室,桂林541004 [3]加拿大地质调查局,渥太华K1A0E8 [4]南京地质矿产研究所,南京210016

出　　处：《岩石学报》2013年第12期4186-4214,共29页Acta Petrologica Sinica

基　　金：国家重点基础研究发展计划项目(2012CB416705);国家自然科学重点基金(41230315);中国地质调查局项目(1212011085407)联合资助

摘　　要：本文对湘南宝山铅锌多金属矿区花岗闪长斑岩及其暗色包体进行了系统的锆石U-Pb年代学、岩石地球化学和SrNd-Hf同位素研究,探讨其岩石成因和构造意义。LA-ICP-MS锆石U-Pb定年表明,宝山花岗闪长斑岩成岩年龄为156~158Ma,暗色包体的形成年龄为155.2±1.4Ma,与寄主岩的成岩年龄一致。宝山花岗闪长斑岩为准铝质花岗岩,富集K、Rb、U等大离子亲石元素,亏损Nb、Ti、P等元素,Nb/Ta平均比值为11.3,(87Sr/86Sr)i值为0.7095~0.7115,εNd(t)值为-7.3^-5.0,t2DM(Nd)值为1.35~1.54Ga,锆石εHf(t)值为-14.0^-9.0。暗色包体呈细粒结构,具浑圆的外形,与寄主花岗闪长斑岩接触界线清晰,具暗色的冷凝边,常见针状磷灰石。暗色包体具较低的SiO2含量(55.46%~57.30%),较高的K2O含量(5.86%~6.90%),富集Rb、Ba、Th、U等大离子亲石元素,亏损Nb、Ta、Ti等元素,Nb/Ta平均比值为15.3,(87Sr/86Sr)i值为0.7062~0.7063,εNd(t)值为-2.1^-1.9,锆石εHf(t)值为-12.1^-4.7。与寄主花岗闪长斑岩相比,暗色包体含有较高的Fe、Mg、V、Cr等相容元素。主微量元素和同位素特征表明,宝山花岗闪长斑岩是由来自经俯冲沉积物熔体交代过的富集岩石圈地幔且富水富钾的底侵基性岩浆与由其引起的下地壳部分熔融形成的长英质岩浆发生混合形成,暗色包体则是来自该底侵基性岩浆与少量长英质岩浆发生混合形成。Sr-Nd同位素模拟表明,宝山花岗闪长质岩浆由大约20%~30%的富集地幔物质和70%~80%的地壳物质组成。892±20Ma继承锆石核的εHf(t)值为+6.0,t DM(Hf)年龄为1.21Ga,与江南造山带东段新元古代岛弧岩浆的Hf同位素特征一致,推断在花岗闪长斑岩的源岩部分熔融过程中有新元古代岛弧岩浆岩物质的加入,新元古代岛弧岩浆带及扬子与华夏陆块弧陆碰撞带从萍乡向南延伸部分可能与郴州-临武断裂相接。在燕山早期(190~150Ma),受古太平洋板块俯冲作用影响,南岭地区处于岩�Zircon U-Pb chronology, Hf isotope, whole rock geochemistry and Sr-Nd isotopes are reported for the granodiorite porphyry and the mafic microgranular enclave （MME） from the Baoshan Pb-Zn polymetallic deposit, southern Hunan Province. LA-ICP-MS zircon U-Pb dating yields crystallization ages of 156~158Ma and 155.21.4Ma for the granodiorite porphyry and MME, respectively, indicating they are coeval. The Baoshan granodiorite porphyry is metaluminous. This porphyry is enriched in LILEs such as K, Rb and U, depleted in Nb, Ti and P, and has an average Nb/Ta ratio of 11.3. It has initial 87Sr/86Sr ratios of 0.7095~0.7115, εNd（t） values of -7.3 to -5.0, t2DM（Nd） ages of 1.35Ga to 1.54Ga, and zircon εHf（t） values of -14.0 to -9.0. The MME is characterized by microgranular texture, oval-like shape, sharp contact with the host rock and darkly chilled margin, and contains needle-like apatite. It has low SiO2 （55.46%~57.30%） but high K2O （5.86%~6.90%）. This MME is enriched in LILEs such as Rb, Ba, Th and U, depleted in Nb, Ta and Ti, and has initial 87Sr/86Sr ratios of 0.7062~0.7063, εNd（t） values of -2.1^-1.9, zircon εHf（t） values of -12.1^-4.7, and relative high Nb/Ta ratio （average of 15.3）. The MME has higher compatible elements, such as Fe, Mg, V and Cr, than the granodiorite. The elemental and isotopic geochemistry suggests that the Baoshan granodiorite porphyry might have been formed by mixing of mafic and felsic member magmas. The mafic member is hydrous and K-rich mafic magma which might be derived from enriched lithospheric mantle source that had been metasomatized by subducting-sediment-derived melts. The felsic member was generated by partial melting of lower crust induced by the underplating of the hydrous and K-rich mafic magma. The MME might be derived from the mafic magma with minor addition of the felsic magma. The modeling using Sr-Nd isotopes shows that the mixture of 20%~30% mafic magma and 70%~80% felsic magma can generate the Baoshan granodiorite porphyry. Inherite

关 键 词：花岗闪长斑岩 暗色包体 地球化学 岩浆混合作用 湘南宝山铅锌多金属矿 

分 类 号：P588.121[天文地球—岩石学] P597.3[天文地球—地质学]