Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution  

作　　者：马征 董晓霞 胡玉峰 张柏松 徐长英 刘艳升 

机构地区：[1]Shandong Province Key laboratory of Plant Nutrition and Fertilizer, Agriculture Resources and Environment Institute,Shandong Academy of Agricultural Science, Jinan 250100,China [2]State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China

出　　处：《Chinese Journal of Chemical Engineering》2013年第12期1370-1375,共6页中国化学工程学报（英文版）

基　　金：Supported by the National Natural Science Foundation of China（21176248）

摘　　要：It is important to know how ILs(ionic liquids)influence organic reaction.In this paper,activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically.Through the study on typical organic reactions happened in ILs,such as Diels-Alder,esterification and Friedel-Crafts reaction,the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.It is important to know how ILs（ionic liquids） influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

关 键 词：ionic liquid activity coefficients at infinite dilution organic reactions 

分 类 号：O646.1[理学—物理化学] O621.25[理学—化学]