中心原子对Keggin结构杂多钼酸盐氧化还原特性的影响  

Effects of Central Atoms on Redox Characteristics of Heteropolymolybdates with Keggin Structure

作　　者：张恒彬[1] 王国甲[1] 吴通好[1] 阎晓斌 胡佶[1] 李树家[1] 

机构地区：[1]吉林大学化学系,130023

出　　处：《高等学校化学学报》1991年第5期656-659,共4页Chemical Journal of Chinese Universities

摘　　要：用电化学方法研究了Keggin结构的砷钼酸盐、磷钼酸盐和硅钼酸盐的氧化还原性质.由实验结果得出中心原子砷、磷和硅对该类杂多钼酸盐氧化还原性质的影响规律。The redox properties of molybdoarsenate, molybdophosphate and molybdosilicate with Keg-gin structure have been studied by electrochemical method. The effect trend of central atoms, arsenic, phosphorus and silicon on the redox characteristics of the heteropolymolybdates was obtained from the experimental results.

关 键 词：杂多钼酸盐 氧化还原 中心原子 

分 类 号：O614.612[理学—无机化学]