含活性基团的环型多硅烷的研究  

Studies of Cyclic Polysilanes Containing Active Group

作　　者：杜作栋[1] 韩同珍[1] 陈剑华[1] 王吉顺[2] 关家锐[2] 

机构地区：[1]山东大学化学系,济南250100 [2]山东大学实验中心

出　　处：《高等学校化学学报》1991年第6期836-839,共4页Chemical Journal of Chinese Universities

基　　金：中国科学院科学基金

摘　　要：以四氢呋喃为溶剂,钠钾合金为缩合剂,使Me_2SiCl_2和(Eto)MeSiCl_2共缩聚,得到一系列含乙氧基的环型多硅烷,通过制备色谱对化合物进行了分离提纯,经质谱、红外光谱、核磁共振谱、紫外光谱证实了化合物的分子结构。对产物的水解活性、热稳定性作了详细的研究。Me_2SiCl_2 and Me(EtO)SiCl_2 were cocondensated by Na/K alloy in THF solvent, and a series of cyclic polysilane containing ethoxy group were obtained. These compounds were purified and separated by preparative chromatography. Their structures were proved by using MS, IR, NMR, UV as the collateral evidences. The hydrolytic reactivities, thermal stabilities of these compounds were studied in detail.

关 键 词：环多硅烷 活性基团 

分 类 号：O627.41[理学—有机化学]