四苯氧基酞菁钴及其吡啶衍生物的配合物的合成和性质  

Synthesis and Properties of Cobalt Tetraphenyloxyphthalocyanine and Its Complexes with Derivatives of Pyridine

作　　者：吴星[1] 刘长庆[1] 张国林[1] 黄明昌[1] 诸洵治 

机构地区：[1]扬州师范学院,扬州225002 [2]上海师范大学

出　　处：《高等学校化学学报》1991年第12期1563-1567,共5页Chemical Journal of Chinese Universities

摘　　要：合成了2,2′,2″,2-四苯氧基酞菁钴配合物[TPhOPeCo(Ⅱ)]及其与吡啶衍生物的配合物[TPhOPcCo(Ⅱ)(L)_2](L=Py,MePy,AnPy),测定了其IR、UV-Vis、热稳定性及其在DMF中的氧化还原半波电位、电子转移速度常数和在不同电位电解下的电子吸收光谱。2,2' , 2'.2'''-Tetraphenyloxyphthalocyanine cobalt [TPhOPcCo(Ⅱ)] and its complexes with derivatives of pyridine [TPhOPcCo (Ⅱ) (L)2] (L = pyridine, 4-methylpyridine, 2-aminopyridine) were synthesized. Their IR, UV-Vis, half-wave potentials (E1/2) and electron transfer rate constants of the redox reactions for the complexes in DMF were measured. The change of UV-Vis spectra for the complexes was studied when electrolysed at different voltages.

关 键 词：酞菁 钴 吡啶衍生物 络合物 

分 类 号：O614.812[理学—无机化学]