绿色离子液体介质中有序分子聚集体构建  

Preparation of the Ordered Molecular Assembly Based on Green Ionic Liquid Media

作　　者：马福民[1] 郭建林[1] 陈晓[2] 李文[1] 阮敏[1] 于占龙[1] 

机构地区：[1]湖北理工学院化学与材料工程学院,矿区环境污染控制与修复湖北省重点实验室,黄石435003 [2]山东大学化学与化工学院,济南250100

出　　处：《科技导报》2014年第1期78-83,共6页Science & Technology Review

基　　金：国家自然科学基金项目(51202082;51272082);湖北省自然科学基金重点项目(2010CDA026);湖北理工学院人才项目(11yjz04R)

摘　　要：离子液体具有很多物理、化学特性且环境友好,被广泛应用于化学、化工、材料、生物、环境等领域。评述了非质子化离子液体、质子化离子液体等作为绿色介质在构建胶束、溶致液晶、囊泡、微乳液和乳状液等有序分子聚集体方面的研究进展。简述了两亲分子和有序分子聚集体的基本概念、分类及发展,对各种离子型表面活性剂、非离子型表面活性剂及聚合物类表面活性剂在非质子化离子液体、质子化离子液体及水溶液中自组装有序分子聚集体的类型、结构、影响因素、驱动力、机制等进行对比分析,并对其应用领域和研究趋势进行展望。The ionic liquid is widely used in various fields due to its special characteristics and the environment-friendly green performance. In this paper, the research progress is reviewed with a focus on the fabrication of the ordered molecular assembly such as micelles, lyotropic liquid crystals, vesicles, microemulsion and emulsion, using the green ionic liquids as the media, including non- protic and protic ionic liquids. Firstly, the basic concepts, the classification and the development of the amphiphilic molecule and the ordered molecular assembly are briefly discussed. Then, the assembly behaviors of a variety of ionic surfactants, nonionic surfactants and polymeric surfactants in the non-protic ionic liquid, the protic ionic liquid and the aqueous solution are compared. The type, the structure, the influencing factors, the driving force, and the mechanism of the ordered molecular assembly are analyzed. Its application areas and research trends in this field are also commented.

关 键 词：表面活性剂 离子液体 有序分子聚集体 绿色介质 

分 类 号：O621.25[理学—有机化学]