非均相稀土有机金属催化剂研究进展  

Research progress inheterogeneous rare earth organometallic catalysts

作　　者：管施恩 徐嘉欣 陈峰[1] 汪臻[1] 陈明真[1] 梁超[1] 张昉[1] 

机构地区：[1]上海师范大学生命与环境科学学院,上海200234

出　　处：《上海师范大学学报（自然科学版）》2013年第6期605-614,共10页Journal of Shanghai Normal University(Natural Sciences)

基　　金：国家自然科学基金(21107071;51273112)

摘　　要：近年来,非均相稀土有机金属催化剂由于其可克服均相稀土有机金属络合物固有的稳定性差以及难以重复使用等缺点,引起了人们的浓厚兴趣和足够重视.着重介绍了非均相稀土三氟磺酸基有机金属催化剂和非均相稀土胺基有机金属催化剂的研究进展及其在精细有机合成中的应用,并对将来稀土有机金属催化剂的设计合成进行了展望.The use of heterogeneous rare earth organometallic catalysts for organic synthesis has attracted much attention recently since they possess the enhanced stability and reusability. In this review, we mainly present the latest developments in the design and synthesis of heterogeneous rare earth triflate catalysts and heterogeneous rare earth amide catalysts and their applications in fine organic synthesis. Also,we discuss the outlook for the design and synthesis of rare earth organometallic catalysts.

关 键 词：稀土有机金属 非均相催化剂 固载化 

分 类 号：O643.3[理学—物理化学]