中国古代透明青瓷釉的可控仿制及呈色规律研究  

Controlled Imitation and Coloration Mechanism of Chinese Ancient Transparent Celadon Glaze

作　　者：王静[1,2] 王芬[1] 李伟东[2] 李强[2] 徐霁明[2] 罗宏杰[2,3] 

机构地区：[1]陕西科技大学材料科学与工程学院,西安710021 [2]古陶瓷科学研究国家文物局重点科研基地中国科学院上海硅酸盐研究所,上海200050 [3]上海大学,上海200050

出　　处：《中国陶瓷》2014年第2期81-84,共4页China Ceramics

基　　金：国家自然科学基金重点项目(51232008;51072109)

摘　　要：参照中国古代越窑透明青瓷釉的化学组成范围,确定基础釉配方。以氧化铁为着色剂,SiC为还原剂,通过自还原的方法制备了呈色可控的透明青瓷釉。利用分光光度计测定了青瓷釉样品在可见光范围内的吸收光谱,分析了釉反射光谱主波长λd、Fe2+特征吸收峰强度以及还原剂加入量之间的相互关系以及,青瓷釉呈色的变化规律,初步实现了可控呈色青瓷釉的制备。In this study, the composition of the parent glaze was determined by refering to the chemical composition of Yue celadon glaze.The transparent celadon glaze was prepared by the mothod of self-destruction with Iron oxide as coloring agent, SiC as reducing agent. Reflection and absorption spectras of the Samples were determined by Spectrophotometer. The relationship between the main wavelength λ d, Peak intensity of Fe^2＋ and the amount of reducing agent was studied. The coloration mechanism of the transparent celadon glaze was deeply discussed

关 键 词：中国古陶瓷 透明青瓷釉 自还原 离子着色 呈色机理 

分 类 号：TQ174.43[化学工程—陶瓷工业]