联苯二酚尾饰锌卟啉的合成及其光谱性质研究  

Synthesis and Spectra Studies of Zinc Porphyrins Tailed by 4,4'-Biphenyldiol

作　　者：江国防[1] 牛平平[1] 张志超[1] 焉保明 郭灿城[1] 

机构地区：[1]湖南大学化学化工学院,湖南长沙410082

出　　处：《湖南大学学报（自然科学版）》2014年第1期112-116,共5页Journal of Hunan University:Natural Sciences

基　　金：国家自然科学基金资助项目(20502005;J120040);湖南省科技资助项目(2012GK3157)

摘　　要：报道了联苯二酚尾饰锌卟啉的合成方法,并研究了其光谱性质.结果发现:目标化合物最大荧光发射波长在650nm左右,位于可见光的红光区,表明所合成的联苯二酚尾饰锌卟啉在可见光的红光部分有较强的荧光发射,这与理想的PDT药物所具有的光学性质一致,有望成为一类优良的光敏剂.The synthesis of zinc porphyrins tailed by 4,4＆#39;-biphenyldiol and their spectral property stud-ies were reported.The results showed that the maximum fluorescence emission wavelength of these zinc porphyrins tailed by 4,4＆#39;-biphenyldiol was about 650 nm,which was located in the visible light region,and was satisfied with the optical properties of the ideal photodynamictherapy drugs.The zinc porphyrins tailed by 4,4＆#39;-biphenyldiol will become an excellent photosensitizer.

关 键 词：金属卟啉 联苯二酚 光谱性质 合成 

分 类 号：O657[理学—分析化学]