镍催化酚衍生物的Suzuki-Miyaura偶联反应研究进展  

Progress of Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions of Phenol Derivatives

作　　者：陈国军[1] 杜建时[2] 

机构地区：[1]长春工程学院理学院,长春130012 [2]吉林大学中日联谊医院血管外科,长春130033

出　　处：《有机化学》2014年第1期65-80,共16页Chinese Journal of Organic Chemistry

摘　　要：过渡金属镍催化的Suzuki-Miyaura偶联反应在有机合成中有着广泛的应用.综述了近年来以过渡金属镍催化的以酚的衍生物为底物的偶联反应的研究进展.主要包括芳基磺酸酯、氨基磺酸芳基酯、碳酸芳基酯、芳基羧酸酯、氨基甲酸芳基酯、芳基磷酸酯、芳醚、杂芳醚和酚盐的偶联反应.Suzuki-Miyaura coupling reaction catalyzed by transition-metal nickel is widely used in organic synthesis. In this review, the development of transition-metal nickel-catalyzed cross-coupling reactions is summarized, mainly including aryl sulfonates, aryl sulfamates, aryl carbonates, aryl carboxylates, aryl carbamates, aryl phosphorus derivatives, aryl ethers, aryl heteroaryl ethers and phenolate.

关 键 词：镍 酚衍生物 Suzuki—Miyaura偶联反应 

分 类 号：O621.251[理学—有机化学]