含PyR_(14)TFSI电解液LiMn_2O_4正极高温电化学性能  

Electrochemical Performance of LiMn_2O_4 in PyR_(14) TFSI Containing Electrolyte at 50 ℃

作　　者：王力臻[1,2] 孙新科[1] 杨许召[1] 张林森[1] 张勇[1,2] 张文静[1] 

机构地区：[1]郑州轻工业学院材料与化学工程学院,河南郑州450000 [2]河南省表界面科学重点实验室,河南郑州450000

出　　处：《电化学》2014年第1期66-72,共7页Journal of Electrochemistry

基　　金：国家自然科学基金(No.21001097);河南省基础与前沿研究项目(No.112300413216)资助

摘　　要：利用差示扫描量热仪(DSC)、电化学工作站、BTS电池测试系统、X-射线衍射仪(XRD)、扫描电子显微镜(SEM)和X射线能量色散谱(EDS)等方法 ,研究了含离子液体N-甲基丁基吡咯烷二(三氟甲基磺酰)亚胺盐(PyR14TFSI)电解液性能以及LiMn2O4电极高温电化学性能.结果表明,随着1 mol·L-1LiPF6EC/EMC/DMC(1:1:1,by volume)中PyR14TFSI添加量的增大,电解液的电导率逐渐增大,添加量为2.5%(by mass)时,电解液DSC曲线由89.3oC、201oC、224oC三个强吸热峰变为116.6 oC和244.3 oC两个强吸热峰;50 oC下,LiMn2O4倍率性能显著提高,2C放电比容量提高16 mAh·g-1,100循环周期后容量保持率为88.3%(提高2.2%).PyR14TFSI添加有利于电极结构的稳定.In this work, with an aim to improve the performance of spinel lithium manganese and to reduce the safety concem of Li-ion battery system, the effects ofN-methyl-N-butylpyrrolidinium bis（trifluoromethylsulfonyl） imide （PyRtaTFSI） on performance of electrolyte and spinel lithium manganes are studied by using differential scanning calorimetry （DSC）, BTS battery test system, electrochemical work station, X-ray diffraction （XRD）, scanning electron microscopy （SEM） and energy dispersive spectroscopy （EDS）. The results indicate that the ionic conductivity of electrolyte is increased with the increase of PYR14TFSI concentration. When the concentration of PyR14TFSI is 2.5% （by mass）, the DSC curves of the PyR14TFSI containing electrolyte are changed from three strong end0thermic peaks （89.3 ℃, 201 ℃, 224 ℃） to two strong endotherrnic peaks （116.6 ℃, 244.3 ℃）. At 50℃, the rate capability is enhanced, the discharge capacity is increased by 16 mAh.g^-1, and the capacity retention is 88.3% （increased by 2.2%） after cycled for 100 times. PyR14TFSI is beneficial to the stability of the electrode structure.

关 键 词：离子液体 尖晶石型锰酸锂 N-甲基丁基吡咯烷二(三氟甲基磺酰)亚胺盐 安全性 

分 类 号：TM912[电气工程—电力电子与电力传动]