Cross-Coupling Reactions of Pyrimidin-2-yl Sulfonates with Phenols and Anilines： An Efficient Approach to C2-Functionalized Pyrimidines  

作　　者：Zhengjun Quan Fuqiang Jing Zhang Zhang Yuxia Da Xicun Wang 

机构地区：[1]Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education, China [2]Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Anning East Road 967#, Lanzhou, Gansu 730070, China

出　　处：《Chinese Journal of Chemistry》2013年第12期1495-1502,共8页中国化学（英文版）

基　　金：We are thankful for the financial support from the National Natural Science Foundation of China，the Natural Science Foundation of Gansu Province，the Scientific and Technological Innovation Engineering Program of Northwest Normal University

摘　　要：Pyrimidin-2-yl sulfonates, as an efficient reaction partner, which can be easily prepared from cheap commercial materials, were coupled with phenols and anilines to give a wide array of C2-aryloxy- and arylaminopyrimidines in good to excellent yields under mild reaction conditions.Pyrimidin-2-yl sulfonates, as an efficient reaction partner, which can be easily prepared from cheap commercial materials, were coupled with phenols and anilines to give a wide array of C2-aryloxy- and arylaminopyrimidines in good to excellent yields under mild reaction conditions.

关 键 词：cross-coupling pyrimindine-2-yl sulfonates C2-aryloxypyrimidines C2-arylaminopyrimidines 

分 类 号：TQ655[化学工程—精细化工] O753.2[理学—晶体学]