Pd-catalyzed cross-coupling of polyfluoroarenes with cyclic vinyl triflates  

Pd-catalyzed cross-coupling of polyfluoroarenes with cyclic vinyl triflates

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作  者:YU YanBo WANG Zhen ZHANG XinGang 

机构地区:[1]Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences [2]College of Agriculture,Inner Mongolia Agricultural University

出  处:《Science China Chemistry》2014年第2期276-281,共6页中国科学(化学英文版)

基  金:financially supported by the National Basic Research Program of China (973 Program,2012CB821600);the National Natural Science Foundation of China (21172242); thesupport of Shanghai institute of Organic Chemistry,the Chinese Academy of Sciences.

摘  要:An effective method for Pd-catalyzed cross-coupling between polyfluoroarenes and cyclic vinyl triflates has been developed.This protocol provides a useful and facile access to polyfluoroarylated cyclic alkenes that are difficult to prepare otherwise.The advantages of this method are its high efficiency and operational simplicity.An effective method for Pd-catalyzed cross-coupling between polyfluoroarenes and cyclic vinyl triflates has been developed. This protocol provides a useful and facile access to polyfluoroarylated cyclic alkenes that are difficult to prepare otherwise. The advantages of this method are its high efficiency and operational simplicity.

关 键 词:C-H bond functionalization cyclic vinyl triflates PALLADIUM polyfluoroarencs 

分 类 号:TB383.3[一般工业技术—材料科学与工程]

 

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