DSA电极电催化氧化降解四环素废水工艺优化  

Optimization of Electro-catalytic Oxidation of Tetracycline Hydrochloride in Aqueous Solution by DSA Electrodes

作　　者：张佳[1] 夏明芳[1,2] 王国祥[1] 朱兆连[2] 江野立[2] 韩睿明[1] 

机构地区：[1]南京师范大学地理科学学院江苏省环境演变及生态建设重点实验室,江苏南京210023 [2]南京大学环境学院污染控制与资源化研究国家重点实验室,江苏南京210093

出　　处：《精细化工》2014年第2期234-239,248,共7页Fine Chemicals

基　　金：国家自然科学基金项目(41173078)~~

摘　　要：以盐酸四环素(TC·HCl)为研究对象,钛基钌铱涂层(IrO2-RuO2/Ti)为阳极,钛板为阴极,电催化氧化降解TC·HCl模拟废水,探讨了初始质量浓度、电流密度、pH、电解质硫酸钠浓度对电催化降解TC·HCl效率的影响。结果表明,电催化氧化可有效降解水中的TC·HCl。提高电流密度,降低TC·HCl初始质量浓度、电解质硫酸钠浓度,可增大TC·HCl去除率。反应的前90 min,pH对去除率无影响,反应90 min后降解效果出现明显差别,pH为3、7和12时,反应300 min去除率分别为92%、100%和72%。降解过程遵循一级反应动力学模型。通过综合各工艺参数下的去除率、能量消耗和电流效率,得出最佳工艺参数为:TC·HCl初始质量浓度300 mg/L、电流密度10 mA/cm2、硫酸钠浓度0.05 mol/L、pH=7,在该条件下反应180 min后TC·HCl去除率达94%。该实验结果为电化学处理制药工业废水提供了基础数据和科学参考。Abstract： Tetracycline HCl（TC · HCl） in artificial wastewater was electrochemically degraded using IrO2-RuO2/Ti as anode and Ti as cathode. The impacts of initial TC ·HCX concentrations, current density, pH values, and electrolyte concentrations on the degradation effect of TC · HCl were investigated. The energy consumption and current efficiency were compared according to operating conditions to reveal the optimal conditions for electrochemical degradation of TC ·HCl. The results show that electro-catalytic oxidation could effectively remove TC · HCl in aqueous solutions. Higher current density, lower initial concentrations of TC · HCl and/or lower concentrations of Na2SO4 as electrolyte could enhance the removal rate of TC ·HCl. During 0 - 90 min of the reaction, pH had no effect on the removal rate. However, after 90 rain, acidic and alkaline conditions both partly inhibited the degradation of TC · HCl,that is,the removal rates at pH 3,7 and 12 were 92% ,100% and 72% respectively after 300 rain. The degradation procedure was in accordance with the first-order kinetic model. Based on the analysis of the removal rate, energy consumption and current efficiency under various operating conditions, the optimal conditions were ascertained as follows：the initial TC · HCl mass concentration of 300 mg/L ,the current density of 10 mA/cm2 ,the Na2SO4 concentration of 0.05moL/L and the pH after 180 min. The · HCl. value of 7. Under such conditions, the removal rate of TC · HCl could present study provides so far the primary data for wastewater management reach 94% against TC·HCl.

关 键 词：电催化 盐酸四环素 降解 反应动力学 水处理技术与环境保护 

分 类 号：TQ085[化学工程] TQ035