掺杂双(N-2-甲基苯基-水杨醛亚胺)合铜(II)配合物的碳糊电极电催化测量过氧化氢(英文)  

Electrocatalytic measurement of H_2O_2 concentration using bis(N-2-methylphenyl-salicyldenaminato)copper(II) spiked in a carbon paste electrode

作　　者：Hossein Khoshro Hamid R. Zare Rasoul Vafazadeh 

机构地区：[1]Department of Chemistry, Yazd University, Yazd, 89195-741, Iran

出　　处：《催化学报》2014年第2期247-254,共8页

摘　　要：The electrochemical behavior of a bis (N-2-methylphenyl-salicyldenaminato)copper (II) complex spiked in a carbon paste electrode (BMPSCu-CPE) and its electrocatalytic reduc-tion of H2 O2 were examined using cyclic voltammetry, chronoamperometry, and differen-tial pulse voltammetry. Cyclic voltammetry was used to study the redox properties of BMPSCu-CPE at various potential scan rates. The apparent charge transfer rate constant and the transfer coefficient for the electron transfer between BMPSCu and the carbon paste electrode (CPE) were 1.9 ± 0.1 s–1 and 0.43, respectively. BMPSCu-CPE had excel-lent electrocatalytic activity for H2 O2 reduction in 0.1 mol/L phosphate buffer solution (pH 5.0), and it decreased the overpotential by 300 mV as compared to CPE alone. The diffusion coefficient and kinetic parameters such as the heterogeneous catalytic electron transfer rate constant and electron transfer coefficient for the reduction of H2 O2 at the BMPSCu-CPE surface were also determined using electrochemical methods. Differential pulse voltammetry showed two linear dynamic ranges of 1.0–10.0 and 10.0–300.0 μmol/L and a detection limit of 0.63 μmol/L H2 O2. The BMPSCu-CPE has excellent repro-ducibility and long term stability, and it was successfully applied for the determination of H2 O2 in two pharmaceutical samples: an antiseptic solution and a hair dying cream.The electrochemical behavior of a bis（N-2-methylphenyl-salicyldenaminato）copper（Ⅱ） complex spiked in a carbon paste electrode （BMPSCu-CPE） and its electrocatalytic reduction of H202 were examined using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry. Cyclic voltammetry was used to study the redox properties of BMPSCu-CPE at various potential scan rates. The apparent charge transfer rate constant and the transfer coefficient for the electron transfer between BMPSCu and the carbon paste electrode （CPE） were 1.9 ＋ 0.1 s-1 and 0.43, respectively. BMPSCu-CPE had excellent electrocatalytic activity for H2O2 reduction in 0.1 mol/L phosphate buffer solution （pH 5.0）, and it decreased the overpotential by 300 mV as compared to CPE alone. The diffusion coefficient and kinetic parameters such as the heterogeneous catalytic electron transfer rate constant and electron transfer coefficient for the reduction of H2O2 at the BMPSCu-CPE surface were also determined using electrochemical methods. Differential pulse voltammetry showed two linear dynamic ranges of 1.0-10.0 and 10.0-300.0 μmol/L and a detection limit of 0.63 Bmol/L H2O2. The BMPSCu-CPE has excellent reproducibility and long term stability, and it was successfully applied for the determination of H2O2 in two pharmaceutical samples： an antiseptic solution and a hair dying cream.

关 键 词：碳糊电极 过氧化氢 甲基苯基 电测量 氢浓度 电催化还原 差分脉冲伏安法 微分脉冲伏安法 

分 类 号：O614.121[理学—无机化学] TQ123.6[理学—化学]