聚醚聚羧酸盐水煤浆分散剂的合成及其性能研究  

Study on Performances and Synthesis of Polyether Polycarboxylate Dispersant for Coal Water Slurry

作　　者：屈倩倩[1,2] 张光华[1,2] 朱军峰[1,2] 卫颖菲[1,2] 

机构地区：[1]教育部轻化工助剂化学与技术重点实验室,陕西西安710021 [2]陕西科技大学化学与化工学院,陕西西安710021

出　　处：《煤炭科学技术》2014年第2期106-109,共4页Coal Science and Technology

基　　金：国家自然科学基金资助项目(21176148);陕西省教育厅重点实验室资助项目(2011JS020);陕西科技大学博士科研启动基金资助项目(BJ13-04)

摘　　要：采用一步合成法,以4种不同相对分子质量(即侧链长度不同)烯丙基聚乙二醇(APEG)、甲基丙烯酸(MAA)为单体,在引发剂过硫酸钾(K2S2O8)作用下直接聚合得到一系列烯丙基聚乙二醇聚醚聚羧酸盐分散剂。通过红外光谱及凝胶渗透色谱等手段对聚合物的结构、相对分子质量及其分布进行了表征和分析,并探讨了不同侧链长度的烯丙基聚乙二醇聚醚聚羧酸盐分散剂对彬长煤成浆性能及黏度的影响。结果表明,该分散剂的最佳合成条件为:引发剂为总单体质量的4%,烯丙基聚乙二醇和甲基丙烯酸物质的量比1∶1,反应温度80℃,反应时间5 h,得出侧链长度为27的烯丙基聚乙二醇聚醚聚羧酸盐分散剂对彬长煤具有更好的分散和稳定作用。A series of allyl polyethylene glycol polycarboxylate dispersants was prepared with four different relative molecular mass allyl al- cohol polyoxyethylene（APEG） and methyl acrylate（MAA） as monomer, K2S208 as initiator and hydroquinone as inhibitor by one step syn- thesis method.The copolymer structures were characterized by infrared spectrum and the relative molecular mass and its distribution was analyzed by gel permeation chromatography.The influences were explored of the different side chain length of dispersants on the slurry per- formance and the apparent viscosity of Binchang coal water sluny.Based on the performance results, the synthesis optimized conditions of copolymer was obtained.The mass ratio of methyl acrylate and ally1 alcohol polyoxyethylene was 1 ： 1, dosage of the initiator was 4% of the monomer quantity ,the polymerization temperature was 80 °C and the reaction keeping time was 5 h.The results showed that polycarboxylic acid disoersant with the side chain length of 27 had better disnersin~ and stabilizing effect to Binchang coal.

关 键 词：水煤浆 分散剂 烯丙基聚乙二醇 聚醚聚羧酸盐 侧链长度 

分 类 号：TQ536[化学工程—煤化学工程]