Subsolidus phase relation in the Bi_2O_3–Fe_2O_3–La_2O_3 system  

Subsolidus phase relation in the Bi_2O_3–Fe_2O_3–La_2O_3 system

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作  者:胡启昌 陈业青 吕佩文 黄丰 王娴 

机构地区:[1]Key Laboratory of Optoelectronic Materials Chemistry and Physics,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

出  处:《Chinese Physics B》2014年第2期400-404,共5页中国物理B(英文版)

基  金:Project supported by the National Basic Research Program of China (Grant No.2010CB933501);the National Natural Science Foundation (NNSF) of China (Grant Nos.51002153,21007070,51102232,61106004,21103191,21203198,and 61306075);the Science and Technology Project of Fujian Province,China (Grant No.2013H0056)

摘  要:Bismuth-containing semiconductor material is a hot topic in photocatalysts because of its effective absorption under the visible light. In this paper, we expect to explore a new bismuth-based photocatalyst by studying the subsolidus phase relations of the Bi2O3-Fe2O3-La2O3 system. The X-ray diffraction data shows that in this ternary system the ternary compound does not exist, while seven binary compounds (including one solid solution series Bi1-xLaxO1.5 with 0.167 〈 x 〈 0.339) are obtained and eight compatibility triangles are determined.Bismuth-containing semiconductor material is a hot topic in photocatalysts because of its effective absorption under the visible light. In this paper, we expect to explore a new bismuth-based photocatalyst by studying the subsolidus phase relations of the Bi2O3-Fe2O3-La2O3 system. The X-ray diffraction data shows that in this ternary system the ternary compound does not exist, while seven binary compounds (including one solid solution series Bi1-xLaxO1.5 with 0.167 〈 x 〈 0.339) are obtained and eight compatibility triangles are determined.

关 键 词:Bi2O3-Fe2O3-La2O3 system phase diagram X-ray diffraction BIFEO3 

分 类 号:O611.3[理学—无机化学]

 

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