亚磷酸三苯酯的合成研究  

Study on synthesis of triphenyl phosphite

作　　者：姜丹蕾[1] 常青[2] 张宁[1] 王兆花[1] 

机构地区：[1]中国石油吉林石化公司研究院,吉林吉林132021 [2]中国石油吉林石化公司仓储中心,吉林吉林132021

出　　处：《化工科技》2013年第6期39-41,共3页Science & Technology in Chemical Industry

摘　　要：以苯酚和三氯化磷为原料合成亚磷酸三苯酯,考察了原料配比、温度和时间等条件对反应的影响,确定了最佳工艺参数∶n（苯酚）∶n（三氯化磷）=2∶1,滴加温度30～35℃,滴加时间1.5～2 h;30～40℃反应2h,130～140℃反应5～6 h.在此条件下,产品的凝固点22～23℃,色号达到20（PtCo）,收率92％～93％.Triphenyl phosphite was synthesized by phenol and phosphorous trichloride. Effects of process parameters, such as raw materials ratio,temperature and time on synthesis process were stud- ied,and the optimal synthesis conditions were defined as follows, mole radio of phenol and phosphor- ous trichloride was 2： 1, dropping temperature was 30--40 ℃, dropping time was 1.5-2 h, holding 30 --35 ℃ for 2 h and 130--140 ℃ for 5-6 h. Under this suitable conditions,solidifying point of product was 22-23 ℃ ,colour number of product can be up to 20（Pt-Co）,yield of product was 92%~93%.

关 键 词：苯酚 三氯化磷 亚磷酸三苯酯 

分 类 号：TQ414.2[化学工程]