N,N′- 双(3-羧基水杨醛叉缩胺乙基)草酰胺均双核铜(II),镍(II)配合物合成和性能研究  

Synthesis and Properties on Homobinuclear Cu(II) and Ni(II) Complexes of N,N′-Bis(3-Carboxyl Salicyl Aminal Ethylene) Oxalamide

作　　者：陶偌偈[1] 娄本勇[1] 李谦[1] 于丽[1] 周绪亚[1] 

机构地区：[1]河南大学化学化工学院,开封475001

出　　处：《无机化学学报》2001年第1期129-133,共5页Chinese Journal of Inorganic Chemistry

基　　金：河南省教委课题!( No.1999150024)。

摘　　要：： The homobinuclear complexes of Cu(II) and Ni(II) with N,N′-bis(3-Carboxyl salicyl aminal ethylene) oxalamide were synthesized, and characterized by elemental analysis, IR spectra, Uv-visible spectra, conductometry, thermogravimetry, and magnetic susceptibility measurement, which indicated the complexes own an oxalic amide bridge-linking structure. Room temperature magnetic moment data show that there are antiferromagnetic spin coupling through oxalic amide conjugated double bond, In DMF, the redox half wave potential of Cu(II) binuclear complexes have been measured by cyclic voltammetry, which proves that the Cu(II) complex has two redox waves.： The homobinuclear complexes of Cu(II) and Ni(II) with N,N′-bis(3-Carboxyl salicyl aminal ethylene) oxalamide were synthesized, and characterized by elemental analysis, IR spectra, Uv-visible spectra, conductometry, thermogravimetry, and magnetic susceptibility measurement, which indicated the complexes own an oxalic amide bridge-linking structure. Room temperature magnetic moment data show that there are antiferromagnetic spin coupling through oxalic amide conjugated double bond, In DMF, the redox half wave potential of Cu(II) binuclear complexes have been measured by cyclic voltammetry, which proves that the Cu(II) complex has two redox waves.

关 键 词：均双核配合物 循环伏安 电化学性能 铜 镍 N-N' 

分 类 号：O614.121[理学—无机化学] O614.813[理学—化学]