羟醛缩合反应中酸碱双功能催化剂的研究进展  

Advance in Acid-Base Bifunctional Catalysts for Aldol Condensation

作　　者：吴丽丽[1] 安华良[1] 梁宁[1] 陈翠娜[1] 耿艳楼[1] 赵新强[1] 王延吉[1] 

机构地区：[1]河北工业大学化工学院,天津300130

出　　处：《化学通报》2014年第2期109-114,共6页Chemistry

基　　金：国家自然科学基金项目(21076059);天津市自然科学基金项目(12CYBJC12800);河北省应用基础研究计划重点基础研究项目(12965642D)资助

摘　　要：概述了羟醛缩合反应中酸碱双功能催化剂的分类、酸碱协同催化作用的主要影响因素并推测了酸碱协同催化反应机理。羟醛缩合反应中酸碱双功能催化剂,按其所提供的酸位和碱位的性质可以分为三类:(1)表面本身兼具酸位和碱位的双功能无机材料,(2)材料本身兼具酸位和碱位的双功能有机材料,(3)通过分别引入酸位和碱位所形成的双功能介孔材料。本文分别对这三类催化剂在羟醛缩合反应中的应用进行了综述;此外,还分析和探讨了酸碱中心的强度匹配、相对位置及空间位阻等因素对酸碱协同催化的影响并推测了酸碱协同催化反应机理;最后,对酸碱双功能催化剂在羟醛缩合反应中的应用前景进行了展望。The recent development of acid-base bifunctional catalysts for aldol condensation was reviewed. According to the properties of acidic and basic active sites three kinds of the acid-base bifunctional catalysts, i. e. inorganic materials with both acidic and basic sites on their surface, organic materials with both acidic and basic site in bulk and mesoporous materials formed by introducing the acidic and basic site into their surface, were introduced. The effect of strength matching, relative position and steric hindrance of the acidic and basic active sites on the acid- base cooperative catalysis and the mechanism of acid-base cooperative catalysis were discussed. In addition, the application of the acid-base bifunctional catalysts in aldol condensation was expected.

关 键 词：羟醛缩合反应 酸碱双功能催化剂 协同催化 

分 类 号：O643.36[理学—物理化学] O621.25[理学—化学]