新型含氯、溴的硅酸酯阻燃剂的合成及性能研究  

Synthesis and Properties of a Novel Silicate Flame Retardant Containing Chlorine and Bromine

作　　者：俞春雷[1] 王彦林[1] 刘颖棋[1] 沈敏杰[1] 

机构地区：[1]苏州科技学院化学与生物工程学院,苏州215009

出　　处：《化学通报》2014年第2期185-187,共3页Chemistry

摘　　要：以三溴苯基环氧丙基醚、四氯化硅及1,3-二氯丙醇为主要原料合成新型含硅、氯、溴三元素的协同高效阻燃剂硅酸三(二氯丙基)三溴苯氧基氯丙基酯。探讨了反应温度、时间及投料比对产率的影响,合适的工艺条件为:三溴苯基环氧丙基醚、四氯化硅及1,3-二氯丙醇的摩尔比为1∶1∶3.5,100℃反应5h,产率达98.0%。用FT-IR、1H NMR表征了产物的结构,并用极限氧指数方法测试了产物的阻燃性能等。A novel efficient flame retardant--tris （dichloropropyl）tribromophenoxychloropropyl silicate was synthesized with tribromophenyl epoxypropyl ether, silicon tetraehloride and 1,3-dichloropropanol as the main raw materials and characterized by FT-IR, 1H NMR. The effects of reaction temperature, time and feed ratio on the reaction yield were investigated. The results showed that the yield of 98.0% could be obtained under the conditions of molar ratio of tribromophenyl epoxypropyl ether, silicon tetrachloride and 1,3-diehloropropanol 1：1：3.5 at 100℃ for 5h. The flame retardant properties of the product were measured by LOI technique.

关 键 词：硅酸酯阻燃剂 三溴苯基环氧丙基醚 四氯化硅 1  3-二氯丙醇 

分 类 号：TQ314.248[化学工程—高聚物工业]