驱蚊功能性包合物的制备及应用  

Preparation and application of inclusion complex with mosquito repellent function

作　　者：陈萌[1,2] 雷克林[1] 王玉娇[2] 李伟[2] 

机构地区：[1]湖北文理学院化学工程与食品科学学院,湖北襄阳441053 [2]武汉纺织大学化学与化工学院,湖北武汉430073

出　　处：《印染》2014年第2期4-8,28,共6页China Dyeing and Finishing

基　　金：湖北省杰出青年基金(2010CDA089)

摘　　要：采用饱和溶液法制备艾蒿精油和一氯均三嗪-β-环糊精(MCT-β-CD)的包合物。通过正交试验得到制备包合物的优化工艺条件:MCT-β-CD:艾蒿精油=10 g:1 mL,包合温度50℃,包合时间4 h,搅拌速率为300 r/min。MCT-β-CD接枝棉织物的单因素试验优化工艺参数为:包合物80 g/L,Na_2CO_325 g/L,尿素10 g/L,焙烘温度140℃,焙烘时间6 min。棉织物的接枝增重率可达5.435%。红外光谱图和热分析表征MCT-β-CD已成功接枝到棉织物上,接枝后的棉织物具有较好的驱蚊效果,且可耐水洗15次以上。The mosquito repellent inclusion complex is prepared by saturated solution method with mugworl essential oil and monochlorotriazinyl-β-cyclodextrin（ MCT-β-CD）. The optimum inclusion process is obtained by orthogonal experiment as fol- lows： MCT-13- CD mugwort essential oil = 10 g ： 1 mL, inclusion at 50 ℃ for 4 h with stirring rate 300 r/min. The grafting process of MCT-β-CD on cotton fabric is optimized by single factor experiment as follows： mosquito repellent inclusion com- plex 80 g/L, Na2CO3 25 g/L, urea 10 g/L, curing at 140 ℃ for 6 min, and the weighting percentage of grafted cotton fabric can reach 5.435%. FT-IR and TG/DSC indicate that MCT-13-CD has been grafted onto the cotton fabrics. The grafted cotton fabric features good mosquito repellent effect and washing durability more than 15 times.

关 键 词：化学整理 艾蒿精油 包合物 驱蚊 棉织物 

分 类 号：TS195.55[轻工技术与工程—纺织化学与染整工程]