BiOI/Bi_2WO_6对甲基橙和苯酚的光催化降解及光催化机理(英文)  

Photocatalytic Degradation and Mechanism of BiOI/Bi_2WO_6 toward Methyl Orange and Phenol

作　　者：崔玉民[1,2] 洪文珊[1] 李慧泉[1,2] 吴兴才[3] 凡素华[1] 朱良俊[1] 

机构地区：[1]阜阳师范学院化学化工学院,阜阳236037 [2]安徽环境污染物降解与监测省级实验室,阜阳236037 [3]南京大学化学系介观化学教育部重点实验室,配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2014年第2期431-441,共11页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.21201037);安徽省高校省级自然科学研究项目(KJ2012A217);环境污染物降解与监测省级实验室校级专项(2012HJJC01ZD)资助项目~~

摘　　要：采用简单的沉积方法制备了不同碘化氧铋含量的BiOI/Bi2WO6光催化剂,通过X射线衍射(XRD)、扫描电子显微镜(SEM)、高分辨透射电子显微镜(HR-TEM)、紫外-可见漫反射光谱(UV-Vis DRS)和BET比表面积测量对其进行了表征。在紫外和可见光的照射下,使用甲基橙和苯酚的光催化降解评价了BiOI/Bi2WO6催化剂的光催化性能。结果表明:与商业P25和纯Bi2WO6相比,13.2%BiOI/Bi2WO6光催化剂具有更高的紫外和可见光催化性能。这明显增加的光催化活性主要归功于光生电子和空穴在Bi2WO6和BiOI界面上的有效转移,降低了电子-空穴对的复合。基于BiOI和Bi2WO6的能带结构,提出了光生载流子的一种转移过程。自由基清除剂的实验表明,·OH,h+,·O2-和H2O2,特别是h+,共同支配了甲基橙和苯酚的光催化降解过程。BiOI/Bi2WO6 photocatalysts with various BiOIamounts were prepared by a simple deposition method and characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM）, high-resolution transmission electron microscopy （HR-TEM）, UV-Vis diffuse reflectance spectroscopy （UV-Vis DRS） and low temperature nitrogen adsorption. The photocatalytic performance of BiOI/Bi2WO6 catalysts was evaluated using the photodegradation of methyl orange （MO） and phenol in an aqueous solution under UVand visible light irradiation. The results indicate that compared with commercial Degussa P25 and pure Bi2WO6, the 13.2% BiOI/Bi2WO6 photocatalyst shows much higher UVand visible light photocatalytic performance. The obviously increased photocatalytic activity could be mainly attributed to the effective transfer of the photogenerated electrons and holes at the interface of Bi2WO6 and BiOI, which reduces the recombination of electron-hole pairs. Atransfer process of photogenerated carriers is proposed based on the band structures of BiOIand Bi2WO6. Radical scavengers experiments demonstrate that ·OH, h＋, ·O2-and H2O2, especially h＋, together dominate the photodegradation process of MOand phenol.

关 键 词：沉积法 BiOI Bi2WO6 光催化 甲基橙 苯酚 

分 类 号：O634[理学—高分子化学]