微波技术在聚合反应中的研究现状  

Research Status of Microwave-Assisted in Polymerization Reactions

作　　者：安保贞[1] 张金生[1] 李丽华[1] 李娜[1] 

机构地区：[1]辽宁石油化工大学石油化工学院,辽宁抚顺113001

出　　处：《化学与粘合》2014年第1期55-59,共5页Chemistry and Adhesion

摘　　要：微波加热因其反应时间短、产量高、副反应少、安全等特点,使微波技术作为一种新技术在有机合成中得到广泛的应用,已成为有机合成领域的研究热点,也为聚合反应的研究提供了新的思维方法。简要介绍了微波反应器的研究进展,对国内外微波辐射在高分子聚合反应中的研究现状进行了综述,主要包括微波辅助活性可控的自由基聚合、开环聚合、逐步聚合和以离子液体为介质的聚合,并指出了微波应用于聚合反应中所需要解决的问题。As the new technology, microwave has been widely used in the organic synthesis for its features of shorter reaction time, higher output, less side effects and security. It has become a research hot-spot in the field of organic synthesis. It also has provided a new way of thought for polymerization studies. In this paper, research progress of microwave reactor was introduced, and research status of microwave radiation used in polymerization reaction throughout the world was summarized, including living and controlled radical polymerizations, ring-opening polymerizations, step-growth polymerizations, reactions in ionic liquids. The problems which would be sloved during the microwave polymerization were pointed out.

关 键 词：微波辐射 聚合反应 研究进展 

分 类 号：TQ039.2[化学工程]