大流量河道的水质荧光指纹变化  

3-D Fluorescence Properties of River with Great Flow Rate

作　　者：谢超波[1] 吴静[1] 曹知平[1] 杨林[1] 钱易[1] 吕清[2] 张仁泉[2] 

机构地区：[1]清华大学环境学院环境模拟与污染控制国家重点实验室,北京100084 [2]苏州环境监测中心站,江苏苏州215000

出　　处：《光谱学与光谱分析》2014年第3期695-697,共3页Spectroscopy and Spectral Analysis

基　　金：国家水体污染控制与治理科技重大专项(2008ZX07313-007);环境模拟与污染控制国家重点联合实验室专项经费(12Y02ESPCT);教育部清华自主科研计划(2014)和江苏省环保科研课题资助

摘　　要：荧光光谱因与水样一一对应而被称为"水质荧光指纹",越来越多地被用于水环境监测。研究了大流量河道A河的水质荧光指纹特征及变化。结果表明,该河的三维荧光光谱中含有三个典型的荧光峰,分别在230/340,280/320和250/450nm附近,而三个峰的强度变化很大,而且有突变的现象。同期的CODMn没有明显变化。研究表明,荧光指纹很适合显示大流量水体的水质变化,且可以弥补常规参数不能反映成分变化的不足,是水质预警的好工具。In the present study ,the three-dimensional fluorescence spectra of River A with great flow rate were investigated . The results showed that there existed three unambiguous peaks in the excitation-emission matrix of River A at λex/λem of around 230/340 ,280/320 and 250/450 nm respectively .The fluorescence intensity varied significantly and had sharp fluctuation some-times .But the CODMn of the samples remained quite stable .This study indicated that fluorescence technique could demonstrate the pollution in the water bodies with great flow rate and furthermore make up for the deficiency of the conventional parameters related to organic pollution ,i .e .invalidation to exhibit the components of pollutants .It is a good tool for the early-warning of the w ater quality .

关 键 词：三维荧光光谱 水体 水质 预警 

分 类 号：X830.2[环境科学与工程—环境工程]