含硅环磷腈的合成与表征研究  

Synthesis and characterization of silicone-cyclophosphazene

作　　者：贺攀[1] 胡玲霞[1,2] 方仕江[1] 

机构地区：[1]浙江大学聚合与聚合物工程研究所,化学工程国家重点实验室(浙江大学),杭州310027 [2]金华职业技术学院制药与材料工程学院,金华321007

出　　处：《化工新型材料》2014年第2期149-151,共3页New Chemical Materials

摘　　要：采用在缚酸剂三乙胺存在下的六氯环三磷腈(HCCTP)与羟基硅油(PDMS-OH)亲和取代反应合成一种新型含硅环磷腈化合物。实验先运用红外和31P-NMR谱图分析技术确定了反应产物为含硅环磷腈。随后考察了多种影响因素包括原料配比、缚酸剂用量、反应温度和时间等对取代反应产率的影响规律,得到了较佳的合成反应条件。另外,通过对产物热失重的分析表明含硅环磷腈化合物的热稳定性较好,可望作为的高效硅系阻燃剂应用。The new kind of silicon-containing cyclophosphazene compound was synthesized from the affinity substi-tution reaction of the hexacyclophosphazene（HCCTP） and hydroxyl terminated polydimethylsiloxane（PDMS-OH）in the presence of acid-binding agent TEA. The compound was assured to be the aim product by the analysis of the infrared ray spectrum（IR） and nuclear magnetic resonance（31 P-NMR）. Then, the effects of a variety of factors including the ratio of raw materials, the amount of acid-binding agent, reaction temperature and time, on the reaction yield were examined and the pre- ferred synthesis conditions were obtained. In addition, the compound was demonstrated to be of good thermal stability ac-cording to the TGA test and thus expected to be applied as highly efficient silicon-based flame retardant.

关 键 词：六氯环三磷腈 羟基硅油 缚酸剂 热稳定性 

分 类 号：O621.3[理学—有机化学]