双杂原子Ti-Mn-ZSM-5分子筛的合成与表征  

Synthesis and characterization of zeolite Ti -Mn - ZSM- 5 containing double heteroatoms

作　　者：霍丽华[1] 赵经贵[1] 马淑杰[2] 

机构地区：[1]黑龙江大学化学化工学院,黑龙江哈尔滨150080 [2]吉林大学化学系,吉林长春130023

出　　处：《黑龙江大学自然科学学报》2000年第4期65-67,共3页Journal of Natural Science of Heilongjiang University

基　　金：黑龙江省自然科学基金资助课题!(9732)

摘　　要：在无碱性离子存在下，以硅溶胶、硫酸钛、硫酸锰为原料，分别采用四丙基溴化胺（ＴＰＡＢｒ）、１，６－己二胺（１，６－ＨＤＡ）及正丁胺（Ｒ－ＮＨ２）模板剂，首次合成了双杂原子Ｔｉ－Ｍｎ－ＺＳＭ－５分子筛，并对产物的物性与结构进行了表征。In the absence of alkali metal ions, the zeolite Ti-Mn-ZSM - 5 containing double heteroatom, with silica sol as Si sources, titanium sulfate and manganese sulfate as the starting materials and tetrapropyl ammomium bromide(TPABr), l, 6 -dihexamine(l, 6 - HDA) and n-butylamine (R-NH2) as the templates, respectively, was synthesized for the first time. Some physical and chemical properties and the structure of the product were characterized by using XRD, SEM, TG-DTA, IR and ESR methods.

关 键 词：双杂原子 Ti-Mn-ZSM-5分子筛 水热合成 合成 表征 

分 类 号：TQ424.25[化学工程]