具有液晶性的杯[4]芳烃衍生物的合成及性质研究  

STUDIES ON SYNTHESIS AND MESOMORPHIC PROPERTIES OF 5 [3',4' DI(HEXADECYLOXY)] PHENYLAZO CALIX [4] ARENE

作　　者：敖波[1] 魏孝强[2] 邹萍[3] 李龙章[2] 彭强[2] 谢明贵[2] 

机构地区：[1]西昌师范高等专科学校化学系,西昌615022 [2]四川大学化学学院,成都610064 [3]四川大学分析测试中心,成都610064

出　　处：《四川大学学报（自然科学版）》2000年第6期950-953,共4页Journal of Sichuan University(Natural Science Edition)

基　　金：国家自然科学基金项目 !( 2 9972 0 32 )

摘　　要：The title compound was synthesized with calix [4] arene and 3,4 dihexadecyloxy benzenediazomium tetrafluoroborate. Its structure was elucidated with elementary analysis, IR and 1 HNMR, and their properties relevant to liquid crystal were determined by using DSC and texture. The phase transition temperature K64M244I.It was found that the compound has the opticity. The specific rotation [α] 25 D=+25.86 (C, 0.58, CHCl 3).The title compound was synthesized with calix [4] arene and 3,4 dihexadecyloxy benzenediazomium tetrafluoroborate. Its structure was elucidated with elementary analysis, IR and 1 HNMR, and their properties relevant to liquid crystal were determined by using DSC and texture. The phase transition temperature K64M244I.It was found that the compound has the opticity. The specific rotation [α] 25 D=+25.86 (C, 0.58, CHCl 3).

关 键 词：液晶材料 杯芳烃衍生物 合成 液晶性 疏水功能 金属离子选择配合 敏化发光 重氮结构 

分 类 号：O625.6[理学—有机化学]