Diffusion and Reaction Model of Catalyst Pellets for Fischer-Tropsch Synthesis  

作　　者：Wu Jianmin Sun Qiwen Zhang Zongsen Pang Lifeng 

机构地区：[1]Yankuang Energy R&D Co., Ltd., State Key Laboratory of Coal Liquefaction and Coal Chemical Technology

出　　处：《China Petroleum Processing & Petrochemical Technology》2013年第4期77-86,共10页中国炼油与石油化工（英文版）

基　　金：Financial support from the National Basic Research Program of China(973 Program,2010CB736203)

摘　　要：The diffusion and reaction phenomenon in a Fe-based catalyst pellet for Fischer-Tropsch synthesis was studied. It was considered that the pores of catalyst pellets were full of liquid wax under Fischer-Tropsch synthesis conditions. The re- actants diffused from the bulk gas phase to the external surface of the pellet, and then the reactants diffused through the wax inside the pellet and reacted on the internal surface formed along the pore passages of the pellet. On the basis of reaction kinetics and double a-ASF product distribution model, a diffusion and reaction model of catalyst pellet was established. The effects of diffusion and reaction interaction in a catalyst pellet, the bulk temperature, the reaction pressure and the pellet size on the reactivity were further investigated. The relationship between the internal diffusion effectiveness factor of spherical catalyst pellet and the Thiele modulus were also discussed. The bulk temperature and pellet size have significant effects on the reactivity, while the pressure shows only a slight influence on the reactivity. The internal diffusion effectiveness factor decreases with an increasing Thiele modulus.The diffusion and reaction phenomenon in a Fe-based catalyst pellet for Fischer-Tropsch synthesis was studied.It was considered that the pores of catalyst pellets were full of liquid wax under Fischer-Tropsch synthesis conditions.The reactants diffused from the bulk gas phase to the external surface of the pellet,and then the reactants diffused through the wax inside the pellet and reacted on the internal surface formed along the pore passages of the pellet.On the basis of reaction kinetics and doubleα-ASF product distribution model,a diffusion and reaction model of catalyst pellet was established.The effects of diffusion and reaction interaction in a catalyst pellet,the bulk temperature,the reaction pressure and the pellet size on the reactivity were further investigated.The relationship between the internal diffusion effectiveness factor of spherical catalyst pellet and the Thiele modulus were also discussed.The bulk temperature and pellet size have significant effects on the reactivity,while the pressure shows only a slight influence on the reactivity.The internal diffusion effectiveness factor decreases with an increasing Thiele modulus.

关 键 词：Fischer-Tropsch synthesis diffusion and reaction catalyst pellet internal diffusion effectiveness factor 

分 类 号：TE624.9[石油与天然气工程—油气加工工程]