2D Naphthalenedisulfonate-cadmiun coordination polymer with2,4,5-tri(4-pyridyl)-imidazole as a co-ligand:Structure and catalytic property  

作　　者：Xing-Wei Wang Hui Guo Meng-Jie Liu Xin-Yi Wang Dong-Sheng Deng 

机构地区：[1]Institute of Resources & Environment,Henan Polytechnic University [2]College of Chemistry and Chemical Engineering.Luoyang Normal University

出　　处：《Chinese Chemical Letters》2014年第2期243-246,共4页中国化学快报（英文版）

基　　金：financial support from the National Natural Science Foundation of China(No.21272109);the Natural Science Foundation of Henan Province (No.112300410138);the Foundation of the Education Department of Henan Province(No.2011B150021);Luoyang Science and Technology Fund

摘　　要：A new 2D coordination polymer, [Cd（tpim）（1,5-nds）]n （1）, was constructed from 1,5-naphthalenedi- sulfonate （1,5-nds）. 2.4,5-tri（4-pyridyl）-imidazole （tpim） and Cd（CH3COO）2.2H2O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of I in the solid state were also investigated.A new 2D coordination polymer, [Cd（tpim）（1,5-nds）]n （1）, was constructed from 1,5-naphthalenedi- sulfonate （1,5-nds）. 2.4,5-tri（4-pyridyl）-imidazole （tpim） and Cd（CH3COO）2.2H2O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of I in the solid state were also investigated.

关 键 词：Crystal structure Organosulfonate Coordination polymer Epoxide ring-opening 

分 类 号：O641.4[理学—物理化学]