微波法合成含1,1’-联萘骨架的对称酰胺型开链冠醚  

The Synthesis of Symmetrical Amide Type Open Chain Crown Ether with 1,1,-Binaphthyl Backbone Under Microwave Radiation

作　　者：苟如虎[1,2] 王亚玲[1] 王喜存[2] 杨汝栋[3] 

机构地区：[1]甘肃民族师范学院化学与生命科学系,甘肃合作747000 [2]西北师范大学甘肃省高分子材料重点实验室,甘肃兰州730070 [3]兰州大学化学化工学院,甘肃兰州730000

出　　处：《宁夏大学学报（自然科学版）》2014年第1期53-55,60,共4页Journal of Ningxia University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(29571013);甘肃省自然科学基金资助项目(ZS021A25006Z);甘肃省青年科技基金资助项目(1107RJYP047);甘肃省环保基金资助项目(GH200216);甘肃民族师范学院院长基金资助项目(10-04)

摘　　要：在微波辐射条件下高效合成了3种含1,1’-联萘骨架的对称酰胺型开链冠醚,产物结构经IR,1 H-NMR进行了表征.结果表明,该方法具有反应步骤短,时间短,产率高等优点,是合成含1,1’-联萘骨架的对称酰胺型开链冠醚的有效方法之一.Three types of symmetrical amide type open chain crown ethers with 1,1 ,-binaphthyl backbone were efficiently synthetized under the condition of microwave radiation. Their chemical structures have been confirmed by means of IR, and 1 H-NMR. The result shows that, with less step, short time and high yield, the method of microwave radiation is an effective way of synthetizing symmetrical amide type open chain crown ethers with 1,1 ,-binaphthyl backbone.

关 键 词：微波辐射 1 1'-联萘 合成 

分 类 号：O614.33[理学—无机化学]