新型氟取代六苯并蔻衍生物的合成及其热稳定性  

Synthesis and Thermal Stability of a Novel Fluorine Substituted Hexa-peri-hexabenzocoronene Derivative

作　　者：杨蕾[1] 张扬[1] 张灯青[1] 李贤英[2] 金武松[1] 

机构地区：[1]东华大学化学化工与生物工程学院,上海201620 [2]东华大学环境科学与工程学院,上海201620

出　　处：《合成化学》2014年第2期204-206,221,共4页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(21172035)

摘　　要：四芳基取代环戊二烯酮与二氟取代二苯乙炔通过Diels-Alder环加成反应制得六芳基取代苯(6);6在路易斯酸催化下通过Scholl环氧化脱氢反应合成了一个新型的氟取代六苯并蔻衍生物———1,3,5,8,10,12,14,17-八氟代六苯并蔻(7),收率70%,其结构经1H NMR,13C NMR和MS表征。TG研究结果表明,7失重5%的温度为452℃。Hexaarylbenzene derivative （6） was prepared by Diels-Alder cycloaddition reaction of tetraaryl cyclopentadienone with 4,4＇-difluorodiphenylacetylenes.A novel fluorine substituted hexaperi-hexabenzocoronene derivative——1,3,5,8,10,12,14,17-octafluoro-hexa-peri-hexabenzocoronene （7） in yield of 70% was synthesized by Scholl cyclodehydrogenation of 6 using FeCl3 asthe catalyst.The structures were characterized by 1H NMR,13C NMR and MS.Thermal stability of 7 was investigated by TG and the results indicated that 5% weight loss temperature was 452 ℃.

关 键 词：六苯并蔻 Scholl环氧化 合成 热稳定性 

分 类 号：O625.15[理学—有机化学] O613.41[理学—化学]