3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑构筑的钴(Ⅱ)、铜(Ⅱ)配合物的晶体结构(英文)  

Crystal Structures of Cobalt(Ⅱ) and Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole

作　　者：储兆晶 白晓光[2] 王玉成[2] 陈金梅[1] 赵红[1] 

机构地区：[1]东南大学化学化工学院,南京211189 [2]北京协和医学院医药生物技术研究所,北京100050

出　　处：《无机化学学报》2014年第4期945-951,共7页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20801012);江苏爱纳吉新能源科技有限公司(No.8507040091)资助项目

摘　　要：以3-氨基-1,4,5,6-四氢吡咯[3,4-c]吡唑(Athpp)为配体合成了2个金属配合物即CoCl4(Athpp)2·2H2O(1)和CuCl4(Athpp)2(2)。用红外、元素分析和X-射线单晶衍射等手段表征了晶体结构。配合物1结晶在P1空间群而配合物2结晶在P21/n空间群。金属中心均采取扭曲八面体构型。此外。Two compounds CoCl4（Athpp）2 ·2H2O （1） and CuCl4（Athpp）2 （2） were respectively obtained by the reactions of 3-amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole （Athpp） with cobalt（n） chlorine and copper（n） chlorine. The compounds have been characterized by FT-IR, elemental analyses and crystal structures. The compound 1 crystallizes in P1 space group and the compound 2 crystallizes in P2 1/n space group. The central metals are adopt distorted octahedral geometry. In addition, the fluorescent spectroscopy of the compounds were studied in solid state at room temperature. CCDC： 961605, 1; 961606, 2.

关 键 词：钴(Ⅱ)配合物 铜(Ⅱ)配合物 晶体结构 吡唑衍生物 

分 类 号：O614.81[理学—无机化学] O614.121[理学—化学]