基于开环易位聚合的线形聚双环戊二烯研究进展  

Research progress in linear polydicyclopentadiene based on the ring- openging metathesis polymerization

作　　者：郭萌[1] 李旭阳[1] 张玉清[1] 

机构地区：[1]河南科技大学高分子科学与纳米技术重点实验室,河南洛阳471003

出　　处：《热固性树脂》2014年第2期46-50,共5页Thermosetting Resin

基　　金：河南省杰出人才创新基金项目(074200510019)资助

摘　　要：综述了国内外双环戊二烯(DCPD)单体开环易位聚合合成线形聚双环戊二烯(L-PDCPD)的路线及所采用的各种催化体系,L-PDCPD合成的影响因素以及L-PDCPD性能等方面的研究进展。L-PDCPD良好的热稳定性、可溶性等特点,使其将在聚合物分子设计和改性上发挥重要作用。The research progress in synthetic routes of linear polydicyclopentadiene （ L - PDCPD） using dicyclo- pentadiene （DCPD） monomer by ring opening metathesis polymerization , various used catalytic systems , factors affecting L - PDCPD synthesis and L - PDCP performance and so on were reviewed. The L - PDCPD had good ther- mal stability, solubility and other characteristics and it wouldl play an important role in the design and modification of the polymer molecule.

关 键 词：线形聚双环戊二烯 开环易位聚合 催化 热稳定性 可溶性 

分 类 号：O631.5[理学—高分子化学]