甲基丙烯酸丁酯在Nd-Al-α,α’-联吡啶催化体系中的聚合反应  

Polymerization of Butyl Methacrylate with Nd-Al-α,α'-Dipyridyl Coordination Catalysts

作　　者：房江华[1] 罗云杰[2] 

机构地区：[1]宁波大学(西区)化学系,宁波315211 [2]宁波高等专科学校,宁波315010

出　　处：《催化学报》2001年第1期23-25,共3页

基　　金：浙江省教委科研基金! (19990 2 17);宁波大学科研基金!(19980 2 3G)资助项目

摘　　要：研究了Nd(naph) 3 Al(i Bu) 3 α,α’ 联吡啶 (naph =环烷酸 )催化体系中甲基丙烯酸丁酯的聚合反应 .用核磁共振和红外光谱表征了聚合物的结构 .用凝胶色谱测定了聚合物的分子量和分子量的分布 .结果表明 ,聚合物的结构以全同和无规为主 ,反应机理为配位聚合 ,聚合反应对单体浓度呈一级关系 ,表观活化能为 30 2kJ/mol.The polymerization of butyl methacrylate (BMA) is carried out by using Nd(naph) 3 Al( i Bu) 3 α, α' dipyridyl as a coordination catalyst, which is prepared from neodymium naphthenate, α, α' dipyridine and triisobutyl aluminium with a molar ratio of 1∶1∶4. The structure of the polybutyl methacrylate is characterized by NMR and IR spectroscopy. The molecular weight and its distribution of the polymer are determined by gel chromatography. These studies reveal that the polymer obtained has mainly isotactic and hetero structure. Coordinate mechanism is proposed for the BMA polymerization by Nd Al α, α' dipyridyl. Kinetic studies show that the BMA polymerization rate is first order with respect to monomer concentration. The apparent activation energy of BMA polymerization reaction is 30 2 kJ/mol.

关 键 词：环烷酸钕 三异丁基铝 联吡啶 配位催化剂 甲基丙烯酸丁酯 配位聚合反应 聚甲基丙烯酸丁酯 

分 类 号：O643[理学—物理化学] O631.3[理学—化学]