添加物对1-甲氧基-2-丙醇催化氧化制甲氧基丙酮反应的影响  

Effects of Additives on Catalytic Oxidation of 1-Methoxy-2-Propanol to Methoxyacetone

作　　者：王军伟[1] 周宁[1] 赵春霞[1] 曹国英[1] 胡信全[1] HU Xinquan 

机构地区：[1]中国科学院大连化学物理研究所,,大连116023 [2]Dalian Institute of Chemical Physics, The Chinese Academy of Sciences,

出　　处：《催化学报》2001年第1期87-88,共2页

摘　　要：The system W Ⅵ H 2O 2 has good selectivity for methoxyacetone in oxidation of 1 methoxy 2 propanol. The effects of acid and base additives on selectivity for methoxyacetone were studied. The results showed that the acid additive, i.e. NaHSO 4, was favorable to Na 2WO 4 H 2O 2 system, while the base additive NEt 3 was favorable to other tungsten compounds. A 71 2% of yield of methoxyacetone with 98 9% of selectivity for methoxyacetone was obtained in Na 2WO 4 H 2O 2 NaHSO 4 MeCOMe oxidation system.The system W-VI-H2O2 has good selectivity for methoxyacetone in oxidation of 1-methoxy-2-propanol. The effects of acid and base additives on selectivity for methoxyacetone were studied. The results showed that the acid additive, i.e. NaHSO4, was favorable to Na2WO4-H2O2 system, while the base additive NEt3 was favorable to other tungsten compounds. A 71.2% of yield of methoxyacetone with 98.9% of selectivity for methoxyacetone was obtained in Na2WO4-H2O2-NaHSO4-MeCOMe oxidation system.

关 键 词：甲氧基丙醇 甲氧基丙酮 过氧化氢 催化氧化 钨酸钠催化剂 催化活性 

分 类 号：O643[理学—物理化学]