等离子体引发聚合固定金属离子亲和膜的制备及其吸附性能  

IMMOBOLIZED METAL ION AFFINITY MEMBRANE PREPARED BY PLASMA-INDUCED GRAFT POLYMERIZATION AND ITS ADSORPTION CHARACTERISTICS

作　　者：柴红[1] 陈欢林[1] 徐立[1] 

机构地区：[1]浙江大学化工学院,浙江杭州310027

出　　处：《化工学报》2001年第2期162-166,共5页CIESC Journal

基　　金：国家自然科学基金资助项目!(No .2 96 76 0 38)

摘　　要：An immobilized metal ion affinity membrane was prepared by plasma-induced graft polymerization of glycidyl methacrylate (GMA) onto a porous polypropylene(PP), followed by chemical conversion of epoxide group of the GMA grafted membrane into an iminodiacetate(IDA) group, and chelation with copper ion. The effect of plasma discharge condition, GMA monomer concentration and grafting time on the degree of GMA grafting was studied and the optimum condition for plasma treatment of membrane was:10 W for 30 s, and that for grafting is 30 h at a concentration of 1 mol· L -1 GMA.Under this condition, a maximum grafting degree of 13.28% was obtained. The spectra of IR and XPS shows that GMA and IDA had been attached to the PP membrane after grafting and coupling. The nonselective adsorption of PP membrane had been significantly reduced after the H 2SO 4 treatment of the IDA coupled membrane. Finally, the isotherm adsorption of bovine serum albumin (BSA) on the immobilized metal ion affinity membrane was measured and the adsorption capacity of BSA increased with the degree of grafting. When BSA concentration was 1080 μg·ml -1 ,the adsorption ability of the affinity membrane with a grafting degree of 5.3% was nearly twice as much as that membrane with a grafting degree of 4.66%.An immobilized metal ion affinity membrane was prepared by plasma-induced graft polymerization of glycidyl methacrylate (GMA) onto a porous polypropylene(PP), followed by chemical conversion of epoxide group of the GMA grafted membrane into an iminodiacetate(IDA) group, and chelation with copper ion. The effect of plasma discharge condition, GMA monomer concentration and grafting time on the degree of GMA grafting was studied and the optimum condition for plasma treatment of membrane was:10 W for 30 s, and that for grafting is 30 h at a concentration of 1 mol· L -1 GMA.Under this condition, a maximum grafting degree of 13.28% was obtained. The spectra of IR and XPS shows that GMA and IDA had been attached to the PP membrane after grafting and coupling. The nonselective adsorption of PP membrane had been significantly reduced after the H 2SO 4 treatment of the IDA coupled membrane. Finally, the isotherm adsorption of bovine serum albumin (BSA) on the immobilized metal ion affinity membrane was measured and the adsorption capacity of BSA increased with the degree of grafting. When BSA concentration was 1080 μg·ml -1 ,the adsorption ability of the affinity membrane with a grafting degree of 5.3% was nearly twice as much as that membrane with a grafting degree of 4.66%.

关 键 词：等离子体引发聚合 固定金属离子 亲和膜 固定铜离子 膜分离 牛血清白蛋白 制备 吸附性能 

分 类 号：TQ028.8[化学工程] Q512.103[生物学—生物化学]