Determination and Correlation of Solubility for D-Xylose in Volatile Fatty Acid Solvents  被引量:1

D-木糖在挥发性脂肪酸溶剂中溶解度的测定(英文)

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作  者:李涛 陈飞雄 江振西 任保增 

机构地区:[1]School of Chemical Engineering and Energy, Zhengzhou University

出  处:《Chinese Journal of Chemical Engineering》2014年第4期429-434,共6页中国化学工程学报(英文版)

基  金:Supported by Science and Technology Breakthrough Major Project in Henan Province(112101210200)

摘  要:The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid + acetic acid(1︰1), formic acid + propionic acid(1︰1), formic acid + n-butyric acid(1︰1), and formic acid + isobutyric acid(1︰1) increases with temperature. The Apelblat equation, the λh model, and the ideal solution equation correlate the solubility data well.The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid+acetic acid (1︰1), formic acid+propionic acid (1︰1), formic acid+n-butyric acid (1︰1), and formic acid+isobutyric acid (1︰1) increases with temperature. The Apelblat equation, theλh model, and the ideal solution equation correlate the solubility data well.

关 键 词:solid-liquid equilibrium SOLUBILITY D-XYLOSE 

分 类 号:O629.1[理学—有机化学]

 

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