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机构地区:[1]School of Chemical Engineering and Energy, Zhengzhou University
出 处:《Chinese Journal of Chemical Engineering》2014年第4期429-434,共6页中国化学工程学报(英文版)
基 金:Supported by Science and Technology Breakthrough Major Project in Henan Province(112101210200)
摘 要:The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid + acetic acid(1︰1), formic acid + propionic acid(1︰1), formic acid + n-butyric acid(1︰1), and formic acid + isobutyric acid(1︰1) increases with temperature. The Apelblat equation, the λh model, and the ideal solution equation correlate the solubility data well.The solubility of D-xylose in formic acid and binary solvents of formic acid with formic acid and acetic acid, propionic acid, n-butyric acid or isobutyric acid was measured in the temperature range from 300.35 to 325.05 K using the synthetic method by a laser monitoring technique at atmospheric pressure. The solid-liquid equilibrium data will provide essential support for industrial design and further theoretical study. The experimental data show that the solubility of D-xylose in formic acid and in the mixtures of formic acid+acetic acid (1︰1), formic acid+propionic acid (1︰1), formic acid+n-butyric acid (1︰1), and formic acid+isobutyric acid (1︰1) increases with temperature. The Apelblat equation, theλh model, and the ideal solution equation correlate the solubility data well.
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