酸性离子液体催化合成二元羧酸酯研究进展  

Research Progress of Dicarboxylic Esters Catalyzed by Acidic Ionic Liquids

作　　者：葛京京[1] 赵地顺[1] 翟建华[1] 张拴力 刘猛帅[1] 李俊盼[1] 胡晶晶[1] 

机构地区：[1]河北科技大学化学与制药工程学院,石家庄050018 [2]石家庄新宇三阳实业有限公司,石家庄051430

出　　处：《材料导报》2014年第5期89-92,97,共5页Materials Reports

基　　金：国家自然科学基金(20576026;21106032)

摘　　要：二元羧酸酯是重要的工业原料和有机化工产品,具有广阔的应用前景,因此开发一种催化活性高、重复使用性能好、后处理简单的催化剂成为近年来的一项重要任务。离子液体作为新型绿色催化剂,在二元羧酸酯研究中表现出良好的发展趋势。综述了近年来离子液体在催化合成二元羧酸酯反应中的研究进展,探索了二元羧酸酯的合成机理,指出了目前离子液体催化剂发展需要解决的瓶颈问题及今后的发展方向。Dicarboxylic acid ester is an important industrial rawmaterial and organic chemical product, it has wide application prospect. The development of catalyst with high catalytic activity, good recycle use, simple post- treatment become an important task in recent years. As new green catalysts, ionic liquids showes a good development trend in the study of dicarboxylic esters. The recent progress of ionic liquids catalyzed the dicarboxylic esters is re- viewed. Catalytic mechanism in dicarboxylic esters is explored. The problems existing in the catalysis of ionic liquids are also discussed, and some suggestions on the solution of these issues are put forward.

关 键 词：二元羧酸酯 催化剂 合成 离子液体 

分 类 号：O643.32[理学—物理化学]